Sodium /ˈsoʊdiəm/ is a chemical element with symbol Na (from Ancient Greek Νάτριο) and atomic number 11. It is a soft, silver-white, highly reactive metal. In the Periodic table it is in column 1 (alkali metals), and shares with the other six elements in that column that it has a single electron in its outer shell, which it readily donates, creating a positively charged atom - a cation.
Sodium has a single valence electron, located in the 3s orbital. For that reason it tends to lose it and form the Na⁺ cation, which acquires the stable electron configuration of neon. This ease of ceding an electron explains that it forms mainly ionic bonds with non-metals and that it is a very reactive metal.
2 Na + 2 H₂O → 2 NaOH + H₂
Sodium reacts vigorously with water and produces sodium hydroxide and hydrogen. The reaction releases heat and the hydrogen can ignite.
2 Na + Cl₂ → 2 NaCl
Sodium metal reacts with chlorine to form sodium chloride, a stable ionic compound.
4 Na + O₂ → 2 Na₂O
In contact with air, sodium tarnishes rapidly due to the formation of oxides on its surface.
| Compound | Formula | Use or importance |
|---|---|---|
| Sodium chloride | NaCl | Common salt; seasoning, preservative and de-icer |
| Sodium hydroxide | NaOH | Caustic soda; soaps and industrial processes |
| Sodium carbonate | Na₂CO₃ | Glass, detergents and water treatment |
| Sodium bicarbonate | NaHCO₃ | Baking, cleaning and antacid products |
The stable and practically exclusive isotope in nature is sodium-23 (²³Na), with 12 neutrons. The other known isotopes are radioactive. Sodium-24 (²⁴Na), for example, is used as a radioactive tracer in some scientific research and analysis applications.
Sodium is abundant in the Earth's crust and appears mainly forming compounds, especially sodium chloride (the same compound that makes up common salt). It is found in seawater, in salt deposits and in numerous minerals. The metal is obtained mainly by electrolysis of molten sodium chloride, a process also carried out through industrial methods such as the Downs process.
Sodium was discovered by Humphry Davy in 1807 by electrolysis. The name comes from soda, while the symbol Na comes from the Latin natrium. Its compounds, such as common salt and caustic soda, were known and used long before the metal was isolated.
Metallic sodium is used as a heat exchanger in some nuclear reactors and as an industrial reagent.
Sodium chloride is used as common salt and preservative; sodium hydroxide in soaps and industrial processes; sodium carbonate in glass and detergents; and bicarbonate in cooking, cleaning and pharmaceutical products.
The sodium ion is essential for fluid balance, nerve impulse transmission and muscle contraction. However, excessive sodium intake, especially through common salt, can favor an increase in blood pressure.
Metallic sodium is dangerous because it reacts with water and moisture, releases hydrogen and can cause fires or burns. It must be handled with due precautions and kept away from water. It should not be confused with sodium chloride, common salt, whose properties and risks are very different.
Sodium compounds are common and many are soluble in water.
When sodium is heated, its outermost electron absorbs thermal energy and jumps to a higher orbital level. When the excited electron returns almost immediately to its ground state, it releases that absorbed energy in the form of light photons. The dominant wavelength of this emission falls in the yellow zone of the visible spectrum. This characteristic light emission makes it easy to identify sodium salts in laboratory analysis.
No. Table salt is sodium chloride (NaCl), a compound formed by sodium and chlorine; sodium is only one of its components. Approximately, 5 grams of salt contain about 2 grams of sodium. Therefore, reducing salt helps reduce sodium, but processed foods, broths, deli meats, sauces and breads should also be monitored, where added sodium can appear without the product tasting especially salty.
Metallic sodium has specialized industrial applications, not domestic ones. It is used as a reducing agent in the extraction of some metals, in chemical synthesis and, in certain nuclear reactors, as a liquid refrigerant due to its excellent heat conduction capacity. It is also used in sodium vapor lamps, recognizable by their characteristic yellowish or orange light. However, most of the sodium consumed by society is used in the form of compounds such as sodium chloride, hydroxide or carbonate.
Because its electron configuration ends in a single electron in the 3s orbital, very weakly retained. By losing it, sodium achieves the stable configuration of the noble gas neon. The energy needed to remove that first electron is low, while removing a second one would require much higher energy, on the order of several thousand kilojoules per mole. Therefore, in its compounds, sodium appears almost always with a single oxidation state, +1, forming the Na⁺ cation.
Sodium reacts vigorously with water and moisture in the air, releasing hydrogen that can ignite and cause fires or burns. That is why pure sodium is stored submerged in an inert liquid, such as kerosene or mineral oil, and should never be handled with bare hands or put in contact with water. This reaction is a classic demonstration of the great reactivity of alkali metals.
Processed and prepared foods are usually the main sources of sodium: deli meats, salty snacks, canned goods, instant soups, cured cheeses, breads, sauces and ready-to-eat meals. Sodium is also contributed by salt added while cooking or at the table and some mineral waters with high mineral content. Checking the labeling —usually expressed in milligrams per serving— and comparing products is the most effective way to control total intake.
Both are alkali metals with a single valence electron and similar properties, but they differ in several aspects. Potassium is heavier, denser and even more reactive than sodium, and its atomic number is 19 versus 11 for sodium. Biologically, both ions are essential and act complementarily: sodium predominates outside cells and regulates pressure and fluid balance, while potassium predominates inside cells and participates in muscle contraction and nerve function.
For the general adult population, a usual reference is not to exceed 2,300 mg of sodium per day, while the WHO proposes a more prudent limit of 2,000 mg daily, equivalent to about 5 g of salt. People with hypertension, kidney disease or specific medical recommendation may need a lower target, often around 1,500 mg. The appropriate figure depends on health status, medication and physical activity level, so it is advisable to consult with a health professional.
Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.