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332.180
74.922 u−3, +3, +5
[Ar] 3d10 4s2 4p3AsArsenic

Arsenic

Arsenic is a chemical element with symbol As and atomic number 33. Arsenic occurs in many minerals, usually in conjunction with sulfur and metals, and also as a pure elemental crystal. Arsenic is a metalloid.

Identity

Atomic mass
74.922 u
Category
Metalloids
Group
15
Period
4
Block
p
Oxidation States
−3, +3, +5
Phase (25 °C)
Solid
Appearance
metallic grey

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p3
Short configuration
[Ar] 3d10 4s2 4p3
Electrons per shell
2, 8, 18, 5
Electronegativity (Pauling)
2.18
Electron affinity
77.7 kJ/mol
1st ionization energy
947 kJ/mol
Ionization energies
947 · 1798 · 2735 · 4837 · 6043… kJ/mol

Physical properties

Melting point
—
Boiling point
—
Density
5.727 g/cm³
Molar heat capacity
24.6 J/(mol·K)

Chemical behavior of arsenic

Arsenic is a metalloid of group 15 that presents oxidation states -3, +3 and +5, the +3 being the most stable and common in its chemistry. Its electronegativity of 2.18 (Pauling scale) is located in an intermediate zone between non-metals and metals. Its predominant bond is covalent, with a tendency to form three flat, planar directed bonds. Exceptions: unlike the non-metals in its group, arsenic does not form the typical series of oxoanions of non-metals, and its grey allotrope has metallic conductive properties, which can confuse its strict classification.

Reactivity

  • 2 As + 3 Cl₂ → 2 AsCl₃

    Chlorine reacts with metallic arsenic to give arsenic(III) chloride, a yellowish volatile liquid that is the precursor of numerous arsenic derivatives.

  • As₂O₃ + 6 Zn → 2 As + 3 ZnO

    Arsenic(III) oxide is reduced by zinc in acidic medium, obtaining elemental arsenic, a process used in the purification and separation of arsenic from other salts.

  • As₂O₃ + 2 NaOH → 2 NaAsO₂ + H₂O

    Arsenic oxide reacts with hot strong base to form sodium arsenite, showing arsenic's amphoteric character in basic medium.

Notable compounds

CompoundFormulaUse or importance
Arsenic(III) oxideAs₂O₃White solid used in laboratory equipment, the textile industry and (historically) herbicides
Arsenic acidH₃AsO₄Oxidizing mineral acid; precursor of arsine salts and arsenic compounds
Arsenic hydrideAsH₃Toxic gas used in the manufacture of arsenic films for semiconductors
Gallium arsenideGaAsEssential semiconductor for LEDs, low-consumption lasers and optical communications

Electron shell distribution

Electron shell distribution diagram of Arsenic.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.AsView in the atom builder

Isotopes

Natural arsenic is monoisotopic, composed solely of the stable isotope 75As (100%), with 42 neutrons. Unlike many elements, there are no other stable isotopes in nature. 75As is non-radioactive and is used as a target in the production of compounds for semiconductors; its constant abundance makes it a stable reference in quantitative analyses by mass spectrometry.

Occurrence and production

Arsenic is relatively abundant in the Earth's crust, with an approximate concentration of 1.8 ppm. It occurs combined in minerals such as realgar (As₂S₂), orpiment (As₂S₃), scorodite (FeAsO₄·2H₂O) and nickel arsenide (NiAs). The metal is not extracted from dedicated primary minerals, but as a byproduct of base-metal refining (copper, lead, tin) and the processing of phosphate minerals. Main production comes from phosphoric acid byproducts and tin coke cinders.

History and origin of the name

Arsenic has been known since antiquity; its name comes from Arabic 'al-zarun' and from Persian 'zarnīk', meaning 'yellow pigment'. The German alchemist Albertus Magnus cultivated it and treated it as a chemical compound in the 12th century. The symbol 'As' comes from the Latin 'arsenicum'. It was first described as an element by the Swiss chemist Johann Joachim Becher in 1648.

Applications and relevance of arsenic

Uses of the element

Metallic arsenic is used in thin semiconductor alloys, such as gallium arsenide, in welding rods and in the manufacture of special lenses. It is also a key component in certain photonic materials and in photoresists for capture.

Uses of its compounds

Gallium arsenide is the most important compound: it enables the manufacture of light-emitting diodes (LEDs), semiconductor lasers, microwave communication components and high-frequency devices. It is also used in the production of solid-state lasers and photodetector systems.

Health, safety and environment

Biological role

Arsenic is highly toxic even in low doses, and its presence in water can constitute a public health problem in regions where aquifers are contaminated. There is no known essential biological function; inorganic arsenic compounds are considered Group 1 carcinogens by the WHO. The handling of metallic arsenic and its salts is controlled by strict legal limits.

Safety

Metallic arsenic is slightly toxic if swallowed; absorption by inhalation is faster and more dangerous. Inorganic compounds carry a high risk of cancer. The metal must be handled with gloves and adequate ventilation, and industrial waste is treated in shielded safety facilities. An important field of knowledge: arsenic toxicity is due to its ability to inhibit enzymes that require arsenate.

Environment

Arsenic does not chemically degrade in the environment, so its accumulation in soils and surface waters is a worrying problem. Extraction activities, industrial chemistry and mining discharges can raise arsenic concentrations in groundwater. Highly effective filtration and removal systems exist, but access to them is uneven in developing countries.

Frequently asked questions about Arsenic

What is arsenic used for in the electronics industry?

Arsenic is used mainly in semiconductor compounds rather than as pure element. One of the most important is gallium arsenide (GaAs), used in certain electronic and optoelectronic devices. This compound enables the manufacture of components that work at high frequencies and devices capable of emitting or detecting light. Its properties are useful in radio frequency applications, optical communications and space technology, where the material's specific performance may be more important than the manufacturing cost.

Why is gallium arsenide useful for emitting light?

Gallium arsenide has a direct bandgap, which facilitates the recombination of electrons and holes releasing energy in the form of photons. This process allows efficient light generation in devices designed for it. In semiconductors with an indirect bandgap, such as silicon, light emission is usually less efficient because additional physical processes are involved. For this reason, certain arsenic-based compounds are used in optoelectronics, although their application depends on wavelength and device design.

How does arsenic modify the properties of semiconductors?

Arsenic can modify the electrical properties of certain semiconductors when incorporated in a controlled way into their crystalline structure. For example, in silicon it usually acts as a donor dopant, providing electrons that contribute to electrical conduction. In other materials, it is part of the semiconductor composition itself, as occurs with gallium arsenide. These two uses are different: in one case a material is modified by doping, and in the other a compound with its own electronic properties is manufactured.

What role do arsenic compounds play in modern technology?

Arsenic compounds have technological applications that go beyond conventional electronics, especially in semiconductor and optoelectronic materials. In addition to gallium arsenide, there are other compounds that can combine with elements such as indium to tune electronic and optical properties. These combinations allow the design of devices to detect light, emit radiation or work in certain frequency bands. Their usefulness depends on composition and material structure, so not all arsenic compounds have the same properties or uses.

What is gallium arsenide and what is it for?

Gallium arsenide is a semiconductor compound formed by gallium and arsenic, with formula GaAs. Unlike silicon, it has a direct bandgap, a feature especially useful for converting electricity into light efficiently. For this reason, it is used in certain LEDs, semiconductor lasers and communication devices. It can also be used in high-frequency circuits. Its manufacture requires precise control of composition and crystal defects to achieve the desired electronic and optical properties.

What is the difference between metallic arsenic and grey arsenic?

Arsenic can occur in different allotropes, that is, different structures formed by the same element. The grey form is the most stable under normal ambient conditions and has a metallic appearance, although its electronic properties do not correspond to those of a conventional conductive metal. There are also yellow and black forms, with different structures and stability. These varieties show that the metallic appearance of a substance is not enough to classify it as a metal, since its internal structure largely determines its physical behaviour.

Why is gallium arsenide used in wireless communications?

Gallium arsenide works well in electronic devices designed to operate at high frequencies. Its charge transport properties allow the manufacture of certain amplifiers and other components used in radio frequency systems. These devices can be found in communication equipment, microwave links and specialized applications. The choice of material depends on factors such as operating frequency, power, efficiency and cost. In many products, gallium arsenide complements silicon rather than completely replacing it.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.