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501.960
118.711 u+2, +4
[Kr] 4d10 5s2 5p2SnTin

Tin

Tin is a chemical element with the symbol Sn (for Latin:stannum) and atomic number 50. It is a main group metal in group 14 of the periodic table. Tin shows a chemical similarity to both neighboring group-14 elements, germanium and lead, and has two possible oxidation states, +2 and the slightly more stable +4.

Identity

Atomic mass
118.711 u
Category
Post-transition metals
Group
14
Period
5
Block
p
Oxidation States
+2, +4
Phase (25 °C)
Solid
Appearance
silvery-white (beta, β) or gray (alpha, α)

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p2
Short configuration
[Kr] 4d10 5s2 5p2
Electrons per shell
2, 8, 18, 18, 4
Electronegativity (Pauling)
1.96
Electron affinity
107 kJ/mol
1st ionization energy
709 kJ/mol
Ionization energies
709 · 1412 · 2943 · 3930 · 7456 kJ/mol

Physical properties

Melting point
231.9 °C (505 K)
Boiling point
2601.8 °C (2875 K)
Density
7.365 g/cm³
Molar heat capacity
27.1 J/(mol·K)

Chemical behavior of tin

Tin is a soft, malleable metal of group 14 with symbol Sn and atomic number 50. There are two main allotropes: white tin, which is metallic, and grey tin, which has semiconductor properties. The transformation between both forms depends on temperature and exposure time.

Reactivity

  • Sn + 2 Cl2 -> SnCl4

    Tin reacts with chlorine to give tetrachloride of tin(IV), a colourless liquid with a sharp odour.

  • Sn + 2 H2SO4 -> SnSO4 + 2 H2O + SO2

    Tin reacts with hot sulfuric acid forming tin sulfate and sulfur dioxide.

Notable compounds

CompoundFormulaUse or importance
Tin(IV) chlorideSnCl4Colourless liquid with a sharp odour; precursor of tin compounds
Tin(II) chlorideSnCl2White solid; used in salts, photographic powders and chemical reduction
Tin dioxideSnO2White solid; used in glass, pigments and ceramics
Tetraethyltin(C2H5)4SnReagent used in paints and lubricants; toxic by bioaccumulation

Electron shell distribution

Electron shell distribution diagram of Tin.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.SnView in the atom builder

Isotopes

Natural tin is composed of twelve stable isotopes: tin-112 (¹¹²Sn, 0.97%), tin-114 (¹¹⁴Sn, 0.66%), tin-115 (¹¹⁵Sn, 0.34%), tin-116 (¹¹⁶Sn, 14.54%), tin-117 (¹¹⁷Sn, 7.68%), tin-118 (¹¹⁸Sn, 24.22%), tin-119 (¹¹⁹Sn, 8.59%), tin-120 (¹²⁰Sn, 32.58%), tin-121 (¹²¹Sn, 4.63%), tin-122 (¹²²Sn, 4.63%), tin-123 (¹²³Sn, 0.97%) and tin-124 (¹²⁴Sn, 5.79%). Tin-120 is the most abundant.

Occurrence and production

Tin is a trace element in the Earth's crust with concentrations of approximately 2-3 ppm. It occurs mainly in the mineral cassiterite (SnO₂) and, to a lesser extent, in stannite. The main reserves are in China, Indonesia, Peru, Bolivia and Brazil. It is obtained mainly as a byproduct of zinc ore refining.

History and origin of the name

Tin has been known since antiquity. It has been used for more than 3,500 years, particularly in the creation of bronze, an alloy of copper and tin. The first records of its use come from the Sulfia culture and the Minoan civilisation. In the modern era, tin was isolated as a chemical element in 1735 by Andreas Sigismund Marggraf, who identified it as a metal distinct from grey tin.

Applications and relevance of tin

Uses of the element

Metallic tin is mainly used in low-melting alloys, electronic soldering and protective coatings. Its main use is in surface-mount soldering (SMT) for printed circuit boards, where it combines low lead content with good thermal properties.

Uses of its compounds

Tin compounds are fundamental in multiple industries: tetraethyltin is used as a reagent in paints and lubricants; tin dioxide is used in glass and ceramics; tin chloride is used in analytical chemistry and medicines; and tin paste is used in liquids and in cork sealing.

Health, safety and environment

Biological role

Tin is not essential for living things. Metallic tin toxicity is relatively low, but organotin compounds can be toxic. Tin ions can be absorbed through skin, lungs and gastrointestinal system. Prolonged exposure to tin compounds can cause liver, kidney damage and affect the central nervous system. Tin moth can cause dermatological irritation.

Safety

Metallic tin is relatively stable, but tin salts are toxic when ingested. Exposure to tin dust can cause irritation of skin, eyes and respiratory system. Tin is not easily soluble in water or evaporates, so its environmental release is mainly through industrial discharges. It must be handled with respiratory protection and hand protection in industrial environments.

Environment

Tin does not degrade in the environment and its accumulation can affect soils and surface waters. Industrial discharges of tin compounds can be dangerous for aquatic life. Tin can adsorb in sediments and affect aquatic organisms. Proper management of mining waste and manufacturing of electronic products is essential to prevent environmental contamination by tin.

Frequently asked questions about Tin

What is tin pest and why can it destroy objects?

Tin pest is a structural transformation that can affect metallic tin when it remains at temperatures low enough for long periods. White metallic and relatively malleable tin can convert to grey tin, a form with a different crystal structure and much more fragile mechanical properties. The transformation can cause objects to crumble or develop powdery areas. The phenomenon depends on temperature, time and other factors that influence conversion rate.

What is bronze and what role does tin play in this alloy?

Bronze is a family of alloys whose main component is usually copper and which traditionally incorporates tin. The addition of the latter modifies properties such as hardness, mechanical resistance and wear behaviour. Composition can vary considerably depending on intended use, and some modern bronzes contain other additional elements. These alloys are used in mechanical parts, bearings, marine components and artistic objects. Their properties do not depend only on tin, but also on proportions and material treatment.

Why can tin have two different crystal structures?

Tin presents two main allotropes under normal pressure conditions: white tin and grey tin. Both are constituted by atoms of the same element, but their crystalline organisation is different, which modifies their physical properties. White tin has metallic behaviour, while the grey presents a more fragile structure and semiconductor properties. The relative stability of each form depends on temperature. This transformation illustrates how a single element can adopt different structures with very different material behaviours.

Why do some modern solders no longer contain lead?

Many current welds are made with tin-based alloys that do not contain lead, especially in electronic products subject to restrictions on certain dangerous substances. Tin is usually combined with metals such as silver and copper to obtain appropriate melting, resistance and reliability properties. However, eliminating lead requires careful control of composition and manufacturing conditions, as different alloys do not behave exactly the same. The choice depends on device type and service requirements.

Why is tin used in electronic soldering?

Tin is an important component of many welding alloys used to join electronic components to printed circuit boards. These alloys allow establishing electrical and mechanical connections without melting the components themselves. Its composition is adjusted to achieve appropriate melting temperatures, resistance and behaviour during manufacturing. Many modern welds use tin mixtures with silver, copper and other metals. The formulation chosen depends on reliability requirements, operating conditions and assembly process.

Why is tin used to coat steel for cans?

Tin can form a protective layer over steel that helps reduce direct contact between it and the container's contents. The coating facilitates the manufacture of corrosion-resistant containers, although its effectiveness depends on the integrity of the layer and operating conditions. The so-called tin foil cans are not made entirely of tin: they consist mainly of steel coated with a thin film of this metal. Container design also influences its durability and protection.

What is the 'tin cry'?

The so-called tin cry is a sound that the metal can produce when it is bent or deformed. It is related to the movement of defects and planes within its crystalline structure during mechanical deformation. This phenomenon is also observed in other soft metals, such as indium, although it is not always audible under the same conditions. The sound does not indicate that tin is emitting a chemical signal: it is a manifestation of the physical processes that take place inside the metal while it changes shape.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.