Tin is a chemical element with the symbol Sn (for Latin:stannum) and atomic number 50. It is a main group metal in group 14 of the periodic table. Tin shows a chemical similarity to both neighboring group-14 elements, germanium and lead, and has two possible oxidation states, +2 and the slightly more stable +4.
Tin is a soft, malleable metal of group 14 with symbol Sn and atomic number 50. There are two main allotropes: white tin, which is metallic, and grey tin, which has semiconductor properties. The transformation between both forms depends on temperature and exposure time.
Sn + 2 Cl2 -> SnCl4
Tin reacts with chlorine to give tetrachloride of tin(IV), a colourless liquid with a sharp odour.
Sn + 2 H2SO4 -> SnSO4 + 2 H2O + SO2
Tin reacts with hot sulfuric acid forming tin sulfate and sulfur dioxide.
| Compound | Formula | Use or importance |
|---|---|---|
| Tin(IV) chloride | SnCl4 | Colourless liquid with a sharp odour; precursor of tin compounds |
| Tin(II) chloride | SnCl2 | White solid; used in salts, photographic powders and chemical reduction |
| Tin dioxide | SnO2 | White solid; used in glass, pigments and ceramics |
| Tetraethyltin | (C2H5)4Sn | Reagent used in paints and lubricants; toxic by bioaccumulation |
Natural tin is composed of twelve stable isotopes: tin-112 (¹¹²Sn, 0.97%), tin-114 (¹¹⁴Sn, 0.66%), tin-115 (¹¹⁵Sn, 0.34%), tin-116 (¹¹⁶Sn, 14.54%), tin-117 (¹¹⁷Sn, 7.68%), tin-118 (¹¹⁸Sn, 24.22%), tin-119 (¹¹⁹Sn, 8.59%), tin-120 (¹²⁰Sn, 32.58%), tin-121 (¹²¹Sn, 4.63%), tin-122 (¹²²Sn, 4.63%), tin-123 (¹²³Sn, 0.97%) and tin-124 (¹²⁴Sn, 5.79%). Tin-120 is the most abundant.
Tin is a trace element in the Earth's crust with concentrations of approximately 2-3 ppm. It occurs mainly in the mineral cassiterite (SnO₂) and, to a lesser extent, in stannite. The main reserves are in China, Indonesia, Peru, Bolivia and Brazil. It is obtained mainly as a byproduct of zinc ore refining.
Tin has been known since antiquity. It has been used for more than 3,500 years, particularly in the creation of bronze, an alloy of copper and tin. The first records of its use come from the Sulfia culture and the Minoan civilisation. In the modern era, tin was isolated as a chemical element in 1735 by Andreas Sigismund Marggraf, who identified it as a metal distinct from grey tin.
Metallic tin is mainly used in low-melting alloys, electronic soldering and protective coatings. Its main use is in surface-mount soldering (SMT) for printed circuit boards, where it combines low lead content with good thermal properties.
Tin compounds are fundamental in multiple industries: tetraethyltin is used as a reagent in paints and lubricants; tin dioxide is used in glass and ceramics; tin chloride is used in analytical chemistry and medicines; and tin paste is used in liquids and in cork sealing.
Tin is not essential for living things. Metallic tin toxicity is relatively low, but organotin compounds can be toxic. Tin ions can be absorbed through skin, lungs and gastrointestinal system. Prolonged exposure to tin compounds can cause liver, kidney damage and affect the central nervous system. Tin moth can cause dermatological irritation.
Metallic tin is relatively stable, but tin salts are toxic when ingested. Exposure to tin dust can cause irritation of skin, eyes and respiratory system. Tin is not easily soluble in water or evaporates, so its environmental release is mainly through industrial discharges. It must be handled with respiratory protection and hand protection in industrial environments.
Tin does not degrade in the environment and its accumulation can affect soils and surface waters. Industrial discharges of tin compounds can be dangerous for aquatic life. Tin can adsorb in sediments and affect aquatic organisms. Proper management of mining waste and manufacturing of electronic products is essential to prevent environmental contamination by tin.
Tin pest is a structural transformation that can affect metallic tin when it remains at temperatures low enough for long periods. White metallic and relatively malleable tin can convert to grey tin, a form with a different crystal structure and much more fragile mechanical properties. The transformation can cause objects to crumble or develop powdery areas. The phenomenon depends on temperature, time and other factors that influence conversion rate.
Bronze is a family of alloys whose main component is usually copper and which traditionally incorporates tin. The addition of the latter modifies properties such as hardness, mechanical resistance and wear behaviour. Composition can vary considerably depending on intended use, and some modern bronzes contain other additional elements. These alloys are used in mechanical parts, bearings, marine components and artistic objects. Their properties do not depend only on tin, but also on proportions and material treatment.
Tin presents two main allotropes under normal pressure conditions: white tin and grey tin. Both are constituted by atoms of the same element, but their crystalline organisation is different, which modifies their physical properties. White tin has metallic behaviour, while the grey presents a more fragile structure and semiconductor properties. The relative stability of each form depends on temperature. This transformation illustrates how a single element can adopt different structures with very different material behaviours.
Many current welds are made with tin-based alloys that do not contain lead, especially in electronic products subject to restrictions on certain dangerous substances. Tin is usually combined with metals such as silver and copper to obtain appropriate melting, resistance and reliability properties. However, eliminating lead requires careful control of composition and manufacturing conditions, as different alloys do not behave exactly the same. The choice depends on device type and service requirements.
Tin is an important component of many welding alloys used to join electronic components to printed circuit boards. These alloys allow establishing electrical and mechanical connections without melting the components themselves. Its composition is adjusted to achieve appropriate melting temperatures, resistance and behaviour during manufacturing. Many modern welds use tin mixtures with silver, copper and other metals. The formulation chosen depends on reliability requirements, operating conditions and assembly process.
Tin can form a protective layer over steel that helps reduce direct contact between it and the container's contents. The coating facilitates the manufacture of corrosion-resistant containers, although its effectiveness depends on the integrity of the layer and operating conditions. The so-called tin foil cans are not made entirely of tin: they consist mainly of steel coated with a thin film of this metal. Container design also influences its durability and protection.
The so-called tin cry is a sound that the metal can produce when it is bent or deformed. It is related to the movement of defects and planes within its crystalline structure during mechanical deformation. This phenomenon is also observed in other soft metals, such as indium, although it is not always audible under the same conditions. The sound does not indicate that tin is emitting a chemical signal: it is a manifestation of the physical processes that take place inside the metal while it changes shape.
Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.