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131.610
26.982 u+3
[Ne] 3s2 3p1AlAluminium

Aluminium

Aluminium (or aluminum; see different endings) is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal. Aluminium is the third most abundant element (after oxygen and silicon), and the most abundant metal, in the Earth's crust.

Identity

Atomic mass
26.982 u
Category
Post-transition metals
Group
13
Period
3
Block
p
Oxidation States
+3
Phase (25 °C)
Solid
Appearance
silvery gray metallic

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p1
Short configuration
[Ne] 3s2 3p1
Electrons per shell
2, 8, 3
Electronegativity (Pauling)
1.61
Electron affinity
41.8 kJ/mol
1st ionization energy
578 kJ/mol
Ionization energies
578 · 1817 · 2745 · 11577 · 14842… kJ/mol

Physical properties

Melting point
660.3 °C (933 K)
Boiling point
2469.8 °C (2743 K)
Density
2.7 g/cm³
Molar heat capacity
24.2 J/(mol·K)

Chemical behavior of aluminium

Aluminum has three outer electrons ([Ne] 3s² 3p¹) and almost always acts as +3, with moderate electronegativity (1.61) and mixed ionic-covalent bonds. It is a very reducing metal that should corrode instantly, but a tiny layer of alumina (Al₂O₃) passivates it, making it resistant: that is why cans do not dissolve. With strong acids and bases the layer yields and reacts violently, and its oxide is amphoteric.

Reactivity

  • 4 Al + 3 O₂ → 2 Al₂O₃

    In air it instantly forms an invisible layer of a few-nanometer alumina that slows corrosion. However, fine dust burns explosively: it is rocket solid propellant.

  • 2 Al + 2 NaOH + 6 H₂O → 2 Na[Al(OH)₄] + 3 H₂

    Lye dissolves the protective layer and the metal releases hydrogen with effervescence, forming aluminate. It is proof of its amphoteric character: it reacts with acids and bases.

  • 2 Al + Fe₂O₃ → Al₂O₃ + 2 Fe

    Thermite: aluminum steals oxygen from iron oxide, releasing extreme heat (~2,500 °C) that melts the iron. It is used to weld rails, and, sadly, in incendiary ammunition.

  • 2 Al + 3 Cl₂ → 2 AlCl₃

    With halogens it reacts with energy, giving covalent halides that fume in moist air. Aluminum chloride is a key catalyst in petrochemicals and organic synthesis.

Notable compounds

CompoundFormulaUse or importance
Alumina (aluminum oxide)Al₂O₃Abrasives, ceramics, rubies and sapphires
Aluminum hydroxideAl(OH)₃Antacids, vaccines (adjuvant) and paper
Aluminum chlorideAlCl₃Petrochemical catalysis and antiperspirants
Aluminum sulfateAl₂(SO₄)₃Drinking water purification and tanning
CryoliteNa₃AlF₆Flux for producing metallic aluminum

Electron shell distribution

Electron shell distribution diagram of Aluminium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.AlView in the atom builder

Isotopes

All natural aluminum is aluminum-27 (²⁷Al), with 14 neutrons: it is monoisotopic. Aluminum-26 (²⁶Al), radioactive with a half-life of 717,000 years, is formed by cosmic rays and heated the first planetesimals; its decay to ²⁶Mg dates the early solar system.

Occurrence and production

It is the most abundant metal in the crust (~8%), but it never appears native: it is always oxidized in bauxite is the main ore, along with clays and feldspars It is obtained by the Bayer process (pure alumina) followed by Hall–Héroult electrolysis in molten cryolite, which consumes huge amounts of electricity: producing it is «solidified electricity».

History and origin of the name

In the time of Napoleon III, aluminum was worth more than gold and was reserved for royal cutlery. In 1886, Charles Martin Hall and Paul Héroult, aged 22 and independently, invented the electrolysis in cryolite that reduced the cost of the metal by a thousand. It owes its name to Roman alum. Today it is the most widely used non-ferrous metal on the planet.

Applications and relevance of aluminium

Uses of the element

Aeroplanes, cans, frames, high-voltage cables and cooking paper: lightweight, conductive and 100% recyclable with only 5% of the original energy. Each recycled can saves the energy of three hours of television.

Uses of its compounds

Alumina is used as an abrasive and rubies are red. Aluminum hydroxide calms heartburn and powers vaccines; aluminum sulfate clarifies drinking water; aluminum zeolites soften water and catalyze gasoline.

Health, safety and environment

Biological role

No known biological function; the body absorbs very little dietary aluminum (tea, antacids) and excretes it. Its possible link to Alzheimer's has not been confirmed in decades of studies, although people with kidney disease should limit it.

Safety

Solid metal is harmless, but fine dust is explosive in suspension, and chronic inhalation damages the lungs (aluminosis). Thermite and melting require extreme protection against projections and heat.

Environment

Bauxite mining deforests, and its red muds are alkaline and toxic if spilled (Ajka, 2010). On the other hand, it is a recycling champion: melting it saves 95% of the energy and can be repeated endlessly without losing quality.

Frequently asked questions about Aluminium

Is it safe to cook with aluminum pots?

Cooking with aluminum utensils is safe under normal conditions, especially if they are anodized or coated. Untreated aluminum can transfer small amounts to food when cooked for a long time with acidic ingredients such as tomato, lemon or vinegar. To minimize that migration, it is advisable to avoid storing acidic foods in unprotected aluminum containers and to replace utensils that are very scratched or deteriorated. The available evidence does not support a causal relationship between aluminum utensils and Alzheimer's.

Can aluminum be recycled infinitely?

Yes. Aluminum is one of the most recyclable materials because it can be melted and turned into new products without significant loss of properties. Recycling it requires much less energy than producing primary aluminum from bauxite. To facilitate the process, cans and trays must be emptied and, if possible, rinsed before being placed in the corresponding container. Containers with food scraps, plastics or adhesives can complicate recycling.

Does aluminum oxidize like iron?

Aluminum oxidizes, but does not corrode in the same way as iron. When it comes into contact with air, it quickly forms a thin layer of aluminum oxide that adheres to the surface and protects the inner metal. That film is almost invisible and prevents further deterioration. Iron, on the other hand, forms porous oxide that falls off and allows corrosion to advance. That is why aluminum is so durable outdoors and in humid environments.

Is it true that aluminum comes from bauxite?

Yes. Aluminum is not normally found in nature as pure metal, but in minerals, and bauxite is the main raw material to obtain it. Through the Bayer process, alumina is extracted from bauxite, and subsequently the Hall–Héroult process separates metallic aluminum by electrolysis. It is an energy-intensive process, which explains the environmental and economic importance of recycling. Recycled aluminum considerably reduces the demand for extraction and electricity.

Why is aluminum so useful for packaging and cans?

Aluminum combines lightness, corrosion resistance, malleability and a good barrier against light, oxygen and moisture. These qualities make it ideal for beverage cans, trays, cooking paper and food containers. In addition, it can be rolled into very thin sheets without breaking and can be recycled repeatedly without losing quality. Its low density also reduces the weight of transport and packaging, which is relevant in logistics, aviation and packaging.

What is the difference between aluminum and steel?

Aluminum is much lighter than steel and resists corrosion better in humid environments because it forms a protective oxide layer. Steel is usually harder, more impact-resistant and cheaper for many structural applications. This is why aluminum predominates in aeronautics, transport, cans and lightweight profiles, while steel is common in construction, machinery and tools. The choice depends on the weight, cost, load and required environmental exposure.

What is aluminum used for besides cans?

In addition to packaging, aluminum is used in car bodies and components, aircraft structures, windows, doors, electrical cables, radiators, bicycles, household appliances and cookware. Its combination of lightness, electrical conductivity and corrosion resistance makes it very versatile. In construction it is used in profiles and facades; in electronics for heat sinks. It also forms alloys with copper, magnesium, silicon or zinc to improve strength and hardness.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.