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231.630
50.942 u+2, +3, +4, +5
[Ar] 3d3 4s2VVanadium

Vanadium

Vanadium is a chemical element with symbol V and atomic number 23. It is a hard, silvery grey, ductile and malleable transition metal. The element is found only in chemically combined form in nature, but once isolated artificially, the formation of an oxide layer stabilizes the free metal somewhat against further oxidation.

Identity

Atomic mass
50.942 u
Category
Transition metals
Group
5
Period
4
Block
d
Oxidation States
+2, +3, +4, +5
Phase (25 °C)
Solid
Appearance
blue-silver-grey metal

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d3
Short configuration
[Ar] 3d3 4s2
Electrons per shell
2, 8, 11, 2
Electronegativity (Pauling)
1.63
Electron affinity
50.9 kJ/mol
1st ionization energy
651 kJ/mol
Ionization energies
651 · 1414 · 2830 · 4507 · 6299… kJ/mol

Physical properties

Melting point
1909.8 °C (2183 K)
Boiling point
3406.8 °C (3680 K)
Density
6 g/cm³
Molar heat capacity
24.9 J/(mol·K)

Chemical behavior of vanadium

Vanadium is a transition metal of group 5 with symbol V and atomic number 23. It is a grey-blue coloured, hard, corrosion-resistant metal with high mechanical resistance. It presents main oxidation states +2, +3, +4 and +5, with +5 being the most stable. It is a fundamental element in metallurgy and electrochemistry industries.

Reactivity

  • 2 V + 5 Cl₂ → 2 VCl₄

    Vanadium reacts with chlorine to form vanadium tetrachloride, a white solid used as precursor of vanadic compounds.

  • V₂O₅ + 2 NaOH → 2 NaVO₃ + H₂O

    Vanadium pentoxide reacts with strong base forming sodium pyrovanadate, showing vanadium's amphoteric character in basic medium.

Notable compounds

CompoundFormulaUse or importance
Vanadium pentoxideV₂O₅Catalyst for the contact process and pigments
Vanadium trichlorideVCl₃Violet solid; precursor of getter and catalysts
Vanadium acetateV(OAc)₂Blue solid; precursor of electrophotography and organic catalysts

Electron shell distribution

Electron shell distribution diagram of Vanadium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.VView in the atom builder

Isotopes

Natural vanadium is composed of a single stable isotope: vanadium-51 (⁵¹V, 100%). It is the only stable isotope of the element. There are also radioactive isotopes, with vanadium-50 very slightly radioactive with an extremely long half-life.

Occurrence and production

Vanadium is a trace element in the Earth's crust, with concentrations of 0.015-0.02 ppm. It appears in minerals such as lead vanadate, vanadite and vorfite. The main reserves are in China, Russia, South Africa, Madagascar and Argentina. It is obtained mainly as a byproduct of iron and zinc refining.

History and origin of the name

Vanadium was discovered in 1801 by Andrés Manuel del Río in Mexico, who initially identified it as a new element. The name derives from the Norse goddess Vanadis. It was later rediscovered in 1830 by Nils Gabriel Sefström, leading to the definitive name vanadium (from 'Vanadis').

Applications and relevance of vanadium

Uses of the element

Vanadium is used mainly in steel alloys for tools, aerospace components, car engines, weldments and structures requiring high resistance. It is also used in redox flow batteries and in the chemical industry as a catalyst.

Uses of its compounds

Vanadium pentoxide is the most important compound, used as a catalyst in the contact process for manufacturing sulfuric acid. It is also used as an industrial pigment and in the manufacture of redox batteries.

Health, safety and environment

Biological role

Vanadium is a trace element needed by some organisms, but not essential for humans in significant amounts. Metallic vanadium is relatively stable and not easily absorbed. Vanadium metal toxicity is low, but vanadium compounds can be toxic, especially vanadium pentoxide, which can irritate skin, eyes and respiratory system.

Safety

Metallic vanadium is relatively stable, but vanadium salts are toxic. Exposure to dust can cause skin, eye and respiratory irritation. It is recommended to use adequate ventilation, respiratory protection and gloves. Industrial waste should be treated in safety facilities.

Environment

Vanadium is in the Earth's crust and does not degrade in the environment. Industrial discharges of vanadium compounds can be dangerous for aquatic life, especially if they accumulate in sediments. Proper management of mining waste and electronic panel manufacturing is essential to prevent environmental contamination by vanadium.

Frequently asked questions about Vanadium

Why add vanadium to steel?

Vanadium allows improving the mechanical properties of certain steels even when added in small amounts. It favours the formation of very fine particles that hinder the movement of dislocations in the metal, increasing its resistance and hardness. It also helps control grain size during heat treatment. For these reasons, vanadium steels are used in tools, car components, parts subjected to large stresses and structures needing high mechanical resistance.

Why is vanadium pentoxide used as a catalyst?

Vanadium pentoxide, chemical formula V₂O₅, is used as a catalyst in important industrial processes. One of the best known is the contact process for manufacturing sulfuric acid, where it facilitates the conversion of sulfur dioxide into sulfur trioxide. Vanadium can temporarily change its oxidation state during the catalytic cycle, helping to transfer oxygen between substances. The catalyst accelerates the reaction without being consumed in net terms, allowing efficient industrial production.

What role does vanadium play in aerospace alloys?

Vanadium is part of some high-performance alloys, including certain titanium alloys and metallic systems designed for demanding conditions. Depending on composition, it can contribute to adjusting mechanical resistance, structural stability and behaviour at high temperatures. These properties are interesting in components where it is important to combine resistance and weight reduction. However, vanadium is not added to all aerospace alloys: its usefulness depends on the properties sought and how it interacts with the other elements.

What importance does vanadium have in electrochemical materials?

Vanadium's different oxidation states allow its compounds to participate in electron transfer reactions, a property exploited in electrochemical technologies. In addition to flow batteries, vanadium oxides are investigated for electrodes, energy storage devices and materials whose conductivity changes with external conditions. Some oxides also present transitions between electronic states with different properties. Not all these uses have the same commercial development: several are still the subject of research to improve their stability, efficiency and cost.

How do vanadium redox flow batteries work?

Vanadium redox flow batteries store energy through reversible chemical reactions of their dissolved ions in liquid electrolytes. During charging and discharging, vanadium changes between different oxidation states, allowing storage or release of electrical energy. Unlike many conventional batteries, the stored energy depends mainly on electrolyte volume, while power depends on the size of the electrochemical cell. This feature allows designing long-duration energy storage systems for power grids and renewable energies.

Why do some vanadium compounds show such different colours?

Vanadium compounds can present green, blue, yellow, orange or violet colours, depending on their chemical composition and the environment of their atoms. One cause is that vanadium can adopt different oxidation states, which modify the electronic transitions responsible for absorbing certain light wavelengths. The solvent, acidity and presence of other substances can also influence colour. That is why changes in tonalities can help study chemical reactions containing vanadium.

Can vanadium help improve solar and wind energy storage?

Yes. One of the most relevant applications of vanadium in the energy sector is redox flow batteries, which can store electricity generated by solar and wind installations and return it when production decreases. Its capacity to utilise large deposits of electrolyte allows expanding stored energy without proportionally increasing the size of the electrochemical cell. In addition, the use of vanadium in both electrolytes can reduce certain problems associated with cross-contamination between chemical species, although cost, efficiency and maintenance remain important factors.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.