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117—
[294] u—
*[Rn] 5f14 6d10 7s2 7p5TsTennessine

Tennessine

Tennessine is a superheavy artificial chemical element with an atomic number of 117 and a symbol of Ts. Also known as eka-astatine or element 117, it is the second-heaviest known element and penultimate element of the 7th period of the periodic table. As of 2016, fifteen tennessine atoms have been observed: six when it was first synthesized in 2010, seven in 2012, and two in 2014.

Identity

Atomic mass
[294] u
Category
Halogens
Group
17
Period
7
Block
p
Oxidation States
Limited experimental data
Phase (25 °C)
Solid

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10 7p5
Short configuration
*[Rn] 5f14 6d10 7s2 7p5
Electrons per shell
2, 8, 18, 32, 32, 18, 7
Electronegativity (Pauling)
—
Electron affinity
166 kJ/mol
1st ionization energy
—

Physical properties

Melting point
449.9 °C (723 K)
Boiling point
609.9 °C (883 K)
Density
7.17 g/cm³
Molar heat capacity
—

Chemical behavior of tennessine

Tennessine is a halogen of period 7 (group 17) that belongs to the set of superheavy elements. Its name comes from the Greek 'tensis' (the one who stretches or lengthens), in reference to the extension of period 7. Its predicted electron configuration is [Rn] 5f14 6d10 7s2 7p5, with oxidation states of -1, +1, +3, +5 and +7. Its estimated electronegativity is approximately 2.0 (Pauling scale), and its chemical behavior is deeply influenced by relativistic effects due to its enormous nuclear charge. Exceptions: theoretical models predict that tennessine may display metallic or semimetallic properties instead of the typical ones of halogens, due to the contraction and stabilization of its electronic orbitals by relativistic effects.

Reactivity

  • Ts2 + 2 e- -> 2 Ts- (electron capture, oxidation states -1, towards ionic bonding)

    Tennessine, like a halogen, can capture electrons to form the ion astatine (Ts-), although this reaction is less favorable than in the lighter halogens due to the heavy nuclear charge and relativistic effects.

  • Ts - O2 -> TsO3 (with strong oxidizing agents, oxidation state +6 and +7)

    Tennessine can react with strong oxidizing agents at high temperatures, forming compounds in higher oxidation states, although the existence and stability of these compounds is theoretical.

  • Ts2 + 2 NaOH -> 2 TsNa + H2O (with hot strong base)

    Tennessine could react with hot strong bases, forming tennessine salts and the corresponding tennessine oxobase, although this reaction is theoretical and has not been observed experimentally.

Notable compounds

CompoundFormulaUse or importance
Tennessine chlorideTsClTheoretical compound; chemical models that predict its formation and reactivity
Tennessine bromideTsBrOxidation state +1 compound; possible intermediate in radioactive reactions
Tennessine oxideTs2O7Oxidation state +7 compound; theoretically predicted following the halogen trend
Tennessine astatine oxideTsAtHeteronuclear oxidation state +1 compound; object of theoretical studies on superheavy chemical bonds

Electron shell distribution

Electron shell distribution diagram of Tennessine.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.TsView in the atom builder

Isotopes

Tennessine presents no stable isotopes: all of its isotopes are radioactive with extremely short half-lives. The most stable known isotope is tennessine-294 (294Ts), with a half-life of approximately 51 milliseconds. Other known isotopes include 293Ts (half-life ~ 26 ms), 292Ts (half-life ~ 35 ms) and 291Ts (half-life ~ 30 ms). All measurements have been carried out in particle reactors and nuclear fission experiments. Such a short life makes any conventional chemical test practically impossible.

Occurrence and production

Tennessine is not found naturally in the Earth's crust: its radioactive isotopes are produced artificially in laboratories through nuclear fusion reactions. The amount produced in each experiment is of a few atoms (1-2 atoms per synthesis). Tennessine is obtained by the fusion of berkelium-249 with calcium-48: 249Bk + 48Ca -> 297Ts* -> 294Ts + 3 n. The main sources are particle accelerators and nuclear research centers. There are no natural reserves or tennessine mines.

History and origin of the name

Tennessine was officially discovered in 2010 by an international team of scientists from the Joint Institute for Nuclear Research in Dubna, Russia, in collaboration with the Lawrence Livermore National Laboratory, USA, and the Oak Ridge National Laboratory, USA, through the fusion of berkelium-249 with calcium-48. The name 'tennessine' comes from the Greek 'tensis' (the one who stretches or lengthens), in reference to the extension of period 7. It is considered the heaviest element discovered to date, with atomic number 117.

Applications and relevance of tennessine

Uses of the element

Tennessine has no known commercial applications due to its radioactivity, extreme scarcity and short half-life. Nevertheless, its study is fundamental to expand knowledge about atomic structure and the chemical properties of superheavy elements. Research on tennessine demonstrates that relativistic effects can alter the predicted periodic properties, which is relevant to understanding the limit of the periodic table.

Uses of its compounds

Tennessine compounds are the object of theoretical and computational research. Predictive models suggest that tennessine compounds could display reactivity patterns distinct from those of the lighter halogens, including the formation of species with oxidation states +1, +3 and +5. Their study includes the possibility of forming covalent bonds with other superheavy elements, which helped to develop theories about ultra-heavy chemistry.

Health, safety and environment

Biological role

Tennessine is not biologically relevant due to its extreme radioactivity, scarcity and fractional-millisecond half-life. There is no evidence that tennessine could integrate into biological systems or perform functions in living organisms. Toxicity studies are not experimentally possible, and any model is based on theoretical calculations. It is assumed that tennessine would disintegrate before producing biological effects if it were exposed to significant levels.

Safety

Tennessine is highly radioactive with a half-life of milliseconds, so its handling requires high-level nuclear security installations and laboratory procedures in controlled environments with radiation detectors and protection systems. Samples must be handled in sealed systems, with real-time detection techniques and automatic handling. The production and stability of these elements are a constant challenge in modern nuclear science. Strict radiological safety and nuclear materials handling regulations must be complied with.

Environment

Tennessine is not found in the natural environment and its extremely short half-life prevents it from accumulating or persisting in any ecosystem. If it were released into the environment, it would rapidly disintegrate through radioactive decay. Environmental studies on tennessine focus on strict control of nuclear research waste and on the safety of the laboratories where these elements are produced.

Frequently asked questions about Tennessine

Will tennessine behave like the other halogens?

Tennessine belongs to the halogen family, but it is not expected to exactly reproduce the behavior of chlorine, bromine or iodine. Its enormous nuclear charge produces relativistic effects that alter the distribution of its electrons and can modify its reactivity. Theoretical models predict important differences with respect to the lighter halogens, including a possible decrease of some characteristic chemical trends of the group. However, the scarcity of experimental data prevents precisely establishing all of its chemical properties.

Has the chemistry of tennessine been experimentally studied?

The chemistry of tennessine remains extremely difficult to investigate because only minimal quantities have been produced and its known isotopes are radioactive. Experiments focus mainly on identifying the generated atoms and studying their decay chains, rather than performing conventional chemical tests. To determine its chemical properties it would be necessary to develop experiments capable of working with extraordinarily small quantities and limited observation times. Therefore, much of what is known about its chemical behavior currently comes from theoretical predictions.

Why does tennessine put the rules of the periodic table to the test?

The periodic table allows identifying chemical trends from the electronic structure of the elements, but these trends are not always maintained in a straightforward way in superheavy atoms. In tennessine, relativistic effects can modify the electronic distribution and alter some properties expected from its membership in the halogen family. Studying it allows checking to what extent the rules developed for lighter elements remain valid and where important deviations appear that require more advanced models.

What can studies of tennessine reveal about the limits of chemical elements?

Investigating tennessine allows exploring how atomic structure changes when nuclei contain a very high number of protons. Scientists study nuclear stability, electronic configurations and predicted chemical properties to better understand the limits of the elements that can be produced. This work also helps to improve the models used to predict the characteristics of even heavier elements. Although tennessine has no known everyday applications, its study contributes to expanding knowledge about the fundamental structure of matter.

Why are relativistic effects so important in tennessine?

In superheavy atoms, the high nuclear charge strongly influences the behavior of electrons, to the point that relativistic effects must be included in the calculations of their electronic structure. These corrections modify the energies and the distribution of the orbitals, which can alter chemical bonds and the expected periodic properties. In tennessine, these effects are essential to predict its behavior and to understand why the trends observed in lighter elements cannot always be extrapolated directly.

What would tennessine look like if it could be observed with the naked eye?

No macroscopic sample of tennessine is available that would allow directly observing its color, luster or texture. Although some models can predict physical properties from its electronic structure, these estimates are not equivalent to experimental observations. Its position among the superheavy elements makes it especially difficult to extrapolate the characteristics of the lighter halogens. Therefore, any illustration representing a specific appearance of tennessine must be understood as a hypothetical representation, not as a photograph or confirmed description of the element.

Could tennessine form molecules similar to those of other halogens?

Lighter halogens form diatomic molecules, such as molecular chlorine (Cl2) and molecular iodine (I2). For tennessine, the formation and properties of an equivalent molecule would be questions of theoretical interest, but they were not experimentally characterized with the same level of detail. Calculations must take into account relativistic effects and the particularities of its chemical bonds. Therefore, it is not correct to assume that tennessine would form molecules with exactly the same stability or reactivity as its lighter homologs.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.