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221.540
47.867 u+2, +3, +4
[Ar] 3d2 4s2TiTitanium

Titanium

Titanium is a chemical element with symbol Ti and atomic number 22. It is a lustrous transition metal with a silver color, low density and high strength. It is highly resistant to corrosion in sea water, aqua regia and chlorine.

Identity

Atomic mass
47.867 u
Category
Transition metals
Group
4
Period
4
Block
d
Oxidation States
+2, +3, +4
Phase (25 °C)
Solid
Appearance
silvery grey-white metallic

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d2
Short configuration
[Ar] 3d2 4s2
Electrons per shell
2, 8, 10, 2
Electronegativity (Pauling)
1.54
Electron affinity
7.29 kJ/mol
1st ionization energy
659 kJ/mol
Ionization energies
659 · 1310 · 2653 · 4175 · 9581… kJ/mol

Physical properties

Melting point
1667.8 °C (1941 K)
Boiling point
3286.8 °C (3560 K)
Density
4.506 g/cm³
Molar heat capacity
25.1 J/(mol·K)

Chemical behavior of titanium

Titanium is a transition metal of group 4 with symbol Ti and atomic number 22. It is a soft, silver-white metal, very resistant to corrosion and with high mechanical resistance relative to its density. It presents main oxidation states +2, +3 and +4, with +4 being the most stable. It is one of the most abundant metals in the Earth's crust.

Reactivity

  • Ti + 2 Cl₂ → TiCl₄

    Titanium reacts with chlorine forming tetrachloride of titanium, a colourless liquid that is used as catalyst and precursor of compounds.

  • Ti + 2 H₂SO₄ → Ti(SO₄)₂ + 2 H₂

    Titanium reacts with hot sulfuric acid, forming titanium sulfate and releasing hydrogen.

Notable compounds

CompoundFormulaUse or importance
Titanium dioxideTiO₂White pigment; used in paints, coatings and sunscreens
Titanium tetrachlorideTiCl₄Colourless liquid; precursor of titanium compounds, chlorination agent
Titanium trioxideTi₂O₃Dark grey solid; used in electrolytes and ceramics

Electron shell distribution

Electron shell distribution diagram of Titanium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.TiView in the atom builder

Isotopes

Natural titanium is composed of five stable isotopes: titanium-46 (⁴⁶Ti, 8.26%), titanium-47 (⁴⁷Ti, 7.44%), titanium-48 (⁴⁸Ti, 73.72%), titanium-49 (⁴⁹Ti, 5.41%) and titanium-50 (⁵⁰Ti, 5.18%). Titanium-48 is the most abundant. There are also short-lived radioactive isotopes.

Occurrence and production

Titanium is the ninth most abundant element in the Earth's crust, with concentrations of about 0.6% by mass. It appears in minerals such as ilmenite (FeTiO₃), rutile (TiO₂) and sphene. The main reserves are in Australia, Brazil, Canada, India, Mozambique and the United States. It is obtained mainly as a byproduct of zinc mineral.

History and origin of the name

Titanium was discovered in 1791 by William Gregor in England. The name derives from the Greek 'titanos', meaning 'giant', in reference to the Greek mythological creature the Titans). It was independently recognised by Martin Heinrich Klaproth in 1795. It was the first element in group 4 of the periodic table.

Applications and relevance of titanium

Uses of the element

Titanium is used in aerospace applications (aircraft and spacecraft structures), dental and medical implants, high-end watchmaking, optics and sporting goods. Its use in the automotive industry is growing due to its low density and high resistance.

Uses of its compounds

Titanium dioxide is the most used compound, applied as a pigment in agricultural, cosmetic and paint products. It is also used in photocatalytic coatings and in sunscreen protectants.

Health, safety and environment

Biological role

Titanium is not essential for living things and is not toxic under normal conditions. In medical implants, its biological compatibility is excellent, and it does not react with living tissues.

Safety

Titanium metal is stable and non-toxic. Fine titanium particles can irritate skin and eyes, so visual protection is recommended in industrial operations. The material does not degrade in the environment and does not accumulate in ecosystems.

Environment

Titanium is an abundant metal and its extraction involves mining waste that requires proper handling. The use of titanium in dental and medical prosthetics is safe and its products are recycled in current recycling centres.

Frequently asked questions about Titanium

Why is titanium used in dental implants and prosthetics?

Titanium is used in dental implants and many prosthetics because it combines mechanical resistance with good compatibility with the body. Its surface forms a very thin oxide layer that limits corrosion and contributes to the material remaining stable in the body. In dental implants, osseointegration can occur, a process by which bone forms a tight union with the implant surface. The result also depends on design, surface treatment and patient conditions.

What makes titanium useful in aeroplanes and spacecraft?

Titanium offers an attractive combination of mechanical resistance, relatively low density and good corrosion behaviour. Some of its alloys maintain useful properties in demanding conditions, so they are used in engine components, structures and aerospace systems. Although usually heavier than aluminium, it can support loads and temperatures that make its use advantageous in certain parts. Its manufacture and machining are costly, so it is selected where its performance justifies that investment.

How is titanium's colour obtained?

Titanium can take on different colours through treatments that modify its oxide layer on the surface. In certain processes, the thickness of this film produces optical interferences making reflected light have different tones, such as blue, violet, gold or green. The colour is not necessarily due to an added pigment, but to the interaction of light with that surface layer. This method is used in jewellery and decorative objects, although the hue depends on the treatment and lighting conditions.

What is the difference between pure titanium and titanium alloys?

Pure titanium stands out for its corrosion resistance and compatibility with the body, while alloys incorporate other elements to modify properties such as strength, hardness or behaviour at different temperatures. For example, some alloys with aluminium and vanadium are used in aerospace and medical components because they offer high mechanical resistance. The choice between pure titanium and an alloy depends on the application: there is no single composition that is the best for all needs.

Why is titanium dioxide used in paints and sunscreens?

Titanium dioxide is a white compound with great capacity to scatter visible light, so it is used as a pigment in paints, coatings and other products. In sunscreens, certain formulations of this compound help attenuate ultraviolet radiation. Its properties depend on particle size, surface coating and how it is incorporated into the product. Thus, titanium dioxide has different applications depending on its formulation and should not be confused with pure metal.

Why does titanium resist corrosion so well?

When titanium is exposed to air or an oxygen-containing medium, its surface spontaneously forms a very thin and adherent layer of titanium oxide. This layer acts as a barrier and makes it difficult for the material to continue reacting with the environment. If the surface suffers damage, the layer can reform under suitable conditions, a behaviour known as passivation. This protection explains its usefulness in chemical equipment, marine applications and implants, although the specific resistance depends on the medium and usage conditions.

Why is titanium difficult to machine and manufacture?

Although its properties are valuable, titanium can be difficult to machine because it conducts heat worse than many other metals and maintains considerable resistance during cutting. This concentrates heat in the tool and can accelerate its wear. In addition, titanium reacts with some gases at high temperatures, so certain processes require a controlled atmosphere. Selection of tools, speeds, cooling and manufacturing techniques is essential to obtain quality parts without unnecessarily increasing costs.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.