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522.100
127.603 u−2, +2, +4, +6
[Kr] 4d10 5s2 5p4TeTellurium

Tellurium

Tellurium is a chemical element with symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur.

Identity

Atomic mass
127.603 u
Category
Metalloids
Group
16
Period
5
Block
p
Oxidation States
−2, +2, +4, +6
Phase (25 °C)
Solid

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p4
Short configuration
[Kr] 4d10 5s2 5p4
Electrons per shell
2, 8, 18, 18, 6
Electronegativity (Pauling)
2.10
Electron affinity
190 kJ/mol
1st ionization energy
869 kJ/mol
Ionization energies
869 · 1790 · 2698 · 3610 · 5668… kJ/mol

Physical properties

Melting point
449.5 °C (723 K)
Boiling point
987.9 °C (1261 K)
Density
6.24 g/cm³
Molar heat capacity
25.7 J/(mol·K)

Chemical behavior of tellurium

Tellurium is a metalloid of group 16 that presents the oxidation states -2, +4 and +6, the +4 and +6 being the most stable. Its electronegativity of 2.10 (Pauling scale) confers intermediate properties between metals and non-metals. Its predominant bond is covalent, with a tendency to form two angular directed bonds. Exceptions: metallic tellurium exhibits semiconductor properties, with intermediate conductivity between metals and insulators, making it useful in specialised electronic applications.

Reactivity

  • Te + 2 Cl2 -> TeCl4

    Tellurium reacts with chlorine to give tetrachloride of tellurium, a white solid that is the precursor of numerous telluric and tellurate derivatives.

  • Te + 2 NaOH -> Na2TeO3 + H2O

    Tellurium reacts with hot strong base to form sodium tellurite, showing tellurium's amphoteric behaviour in basic medium.

  • Te + 2 HNO3 -> H2TeO3 + 2 NO2

    Tellurium reacts with concentrated nitric acid, being oxidised to tellurite, a stable tellurium oxide.

Notable compounds

CompoundFormulaUse or importance
Cadmium tellurideCdTeEssential semiconductor for thin-film solar panels
Bismuth tellurideBi2Te3Key thermoelectric material for cooling and energy generation
Zinc tellurideZnTeN-type semiconductor used in optoelectronic devices
Hydrogen tellurideH2TeToxic gas; intermediate in tellurium chemical processes

Electron shell distribution

Electron shell distribution diagram of Tellurium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.TeView in the atom builder

Isotopes

Natural tellurium is composed of eight stable isotopes: tellurium-120 (¹²⁰Te, 0.09%), tellurium-122 (¹²²Te, 2.55%), tellurium-123 (¹²³Te, 0.89%), tellurium-124 (¹²⁴Te, 4.74%), tellurium-125 (¹²⁵Te, 7.07%), tellurium-126 (¹²⁶Te, 18.84%), tellurium-128 (¹²⁸Te, 31.74%) and tellurium-130 (¹³⁰Te, 34.08%). The most abundant is ¹³⁰Te. There are no environmentally relevant radioactive isotopes; its constant abundance makes it a stable reference in quantitative analyses by mass spectrometry.

Occurrence and production

Tellurium is a very scarce element, with a concentration in the Earth's crust of about 0.001 ppm. It occurs mainly combined in Cotellite (TeS₂) and tellurite (Te). It is obtained as a byproduct of copper and lead refining, in processes where it appears in small amounts. The main reserves are in China, Russia, Canada and the United States. Tellurium never appears free in nature: it is always combined in base metal minerals.

History and origin of the name

Tellurium was discovered in 1782 by the Austrian chemist Franz-Joseph Müller von Reichenstein, who found it in a gold mine in Transylvania. In 1798, Martin Heinrich Klaproth confirmed it and independently baptised it as tellurium, from the Latin 'tellus' (earth). It was one of the elements discovered in the transition between carbon and mercury in the 18th century.

Applications and relevance of tellurium

Uses of the element

Tellurium is added in small amounts to certain alloys to improve their machinability, helping to modify the way chips break and facilitating cutting operations in steels and copper alloys.

Uses of its compounds

Cadmium telluride (CdTe) allows the manufacture of thin-film photovoltaic panels, while bismuth telluride-based materials are used in thermoelectric devices for localised cooling and precise temperature control. These applications take advantage of suitable electrical, optical and thermal properties for specific applications.

Health, safety and environment

Biological role

Tellurium is not essential for living things. Metallic tellurium and its compounds are toxic, especially hydrogen telluride (H₂Te), which is highly toxic and corrosive. Exposure must be controlled through adequate ventilation, respiratory protection and gloves. There is no evidence of biological function; tellurium is mainly excreted through metabolism.

Safety

Metallic tellurium is stable, but its compounds are toxic and can cause irritation to skin, eyes and the respiratory system. Hydrogen telluride is a toxic and corrosive gas that requires handling in local ventilation systems. Tellurium must be handled in well-ventilated areas, with appropriate personal protective equipment and rigorous control of environmental exposure.

Environment

Tellurium does not degrade in the environment and its accumulation can affect soils and surface waters. Industrial discharges of tellurium compounds can be dangerous for aquatic life. Appropriate filtration systems and appropriate waste management technologies are essential to prevent pollution. Tellurium in metallic alloys is considered a stable and safe compound when used properly.

Frequently asked questions about Tellurium

What is tellurium used for?

Tellurium is used in thermoelectric materials, solar cells, metallic alloys and specialised electronic applications. Many of its uses are based on compounds, such as cadmium telluride, used in certain photovoltaic panels, and bismuth telluride, used in thermoelectric modules. It can also be added to some alloys to modify their machinability. Its technological importance derives from the ability of its compounds to present appropriate electrical, optical and thermal properties for specific applications.

What thermoelectric properties does tellurium have?

Tellurium forms compounds capable of converting temperature differences into electricity and, conversely, using electricity to transfer heat. An important example is bismuth telluride, used in thermoelectric devices for localised cooling and precise temperature control. The efficiency of these materials depends on their electrical conductivity, thermal conductivity and ability to generate an electric voltage when facing a temperature difference. Composition and microstructure are adjusted to improve performance within the expected temperature range.

What is the difference between tellurium and telluride?

Tellurium is a chemical element, while a telluride is a compound that contains tellurium combined with another element, normally in a structure where it displays a characteristic chemical behaviour. For example, cadmium telluride contains cadmium and tellurium and is used as a semiconductor in solar cells. Bismuth telluride, on the other hand, has thermoelectric applications. Although both materials contain tellurium, their properties are different because they depend on composition, chemical bonds and the crystalline structure of the compound.

What role does tellurium play in renewable energy technologies?

Tellurium participates in energy technologies through semiconductor compounds used in certain solar cells and thermoelectric systems. Cadmium telluride allows the manufacture of thin-film photovoltaic panels, while materials based on bismuth telluride can convert thermal differences into electricity. These applications take advantage of different properties: one converts light into electrical energy and the other uses temperature gradients. The design of each technology depends on efficiency, cost, durability and the specific requirements of the installation.

What is cadmium telluride and how is it used in solar panels?

Cadmium telluride (CdTe) is a semiconductor compound used to manufacture thin-film solar cells. Its ability to absorb light allows the construction of relatively thin photovoltaic layers, which convert light energy into electricity. In these devices, CdTe is part of a multi-layer structure designed to separate the electric charges generated by light. This technology offers an alternative to crystalline silicon-based panels, with its own manufacturing processes and module-specific characteristics.

Why is tellurium added to some metallic alloys?

Tellurium can be added in small amounts to certain alloys to improve their behaviour during machining. In some steels and copper alloys, it helps to modify the way chips break and can facilitate cutting operations. This is useful for manufacturing components with precise geometries through industrial processes. However, the effect depends on the total composition and manufacturing process, so tellurium is not generally added to all metals, but to formulations destined for specific applications.

How does tellurium behave with electricity?

Elemental tellurium presents different electrical behaviour from conventional metallic conductors and insulators. Its behaviour depends on the crystalline structure, temperature and measuring conditions. In addition, many tellurium compounds possess semiconductor properties that can be used in electronic devices, sensors and photovoltaic systems. In these materials, conductivity can vary according to composition and the presence of defects or impurities. That is why tellurium is especially interesting as a component of functional materials, rather than as a general substitute for metallic conductors.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.