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512.050
121.76 u−3, +3, +5
[Kr] 4d10 5s2 5p3SbAntimony

Antimony

Antimony is a chemical element with symbol Sb (from Latin:stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were used for cosmetics; metallic antimony was also known, but it was erroneously identified as lead upon its discovery.

Identity

Atomic mass
121.76 u
Category
Metalloids
Group
15
Period
5
Block
p
Oxidation States
−3, +3, +5
Phase (25 °C)
Solid
Appearance
silvery lustrous gray

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p3
Short configuration
[Kr] 4d10 5s2 5p3
Electrons per shell
2, 8, 18, 18, 5
Electronegativity (Pauling)
2.05
Electron affinity
101 kJ/mol
1st ionization energy
834 kJ/mol
Ionization energies
834 · 1595 · 2440 · 4260 · 5400… kJ/mol

Physical properties

Melting point
630.6 °C (904 K)
Boiling point
1634.8 °C (1908 K)
Density
6.697 g/cm³
Molar heat capacity
25.2 J/(mol·K)

Chemical behavior of antimony

Antimony is a metalloid of group 15 that presents the oxidation states -3, +3 and +5, the +3 being the most stable and most frequent in its chemistry. Its electronegativity of 2.05 (Pauling scale) configures it as an element with properties intermediate between metals and non-metals. Its predominant bond is covalent, with a tendency to form three flat directed bonds. Exceptions: unlike the non-metals of its group, metallic antimony presents moderate electrical conductivity and semiconductor behaviour.

Reactivity

  • 2 Sb + 3 Cl2 -> 2 SbCl3

    Chlorine reacts with metallic antimony to give trichloride of antimony(III), a white volatile solid that is the precursor of numerous arsenicic and antimonic derivatives.

  • Sb2O3 + 6 NaOH -> 2 NaSbO2 + 3 H2O

    Antimony oxide reacts with hot strong base forming sodium arsenite, showing antimony's amphoteric character in basic medium.

  • Sb2O3 + 6 HCl -> 2 SbCl3 + 3 H2O

    Antimony oxide dissolves in strong hydrochloric acid, evidencing its capacity to act as an acidic oxide in acidic medium.

Notable compounds

CompoundFormulaUse or importance
Antimony trichlorideSbCl3White volatile solid; precursor of antimonic derivatives and special materials
Antimony(III) oxidesSb2O3Most stable oxide; used in flame retardants and industrial reagents
Sodium arseniteNaAsO2Soluble salt; used in metallurgical processes and textile and dermatological industries
Sodium antimonateNaSbO3Soluble compound; used in historic ceramic, glassware and cosmetic processes

Electron shell distribution

Electron shell distribution diagram of Antimony.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.SbView in the atom builder

Isotopes

Natural antimony is composed of two stable isotopes: antimony-121 (¹²¹Sb, 57.21%) and antimony-123 (¹²³Sb, 42.79%). Both are non-radioactive and stable. There are no environmentally relevant radioactive isotopes; the proportion of both isotopes is relatively equal in the Earth's crust, which makes them a stable reference in quantitative analyses by mass spectrometry.

Occurrence and production

Antimony is relatively scarce, with a concentration of about 0.2 ppm in the Earth's crust. It occurs mainly combined in Stibnite (Sb₂S₃), kermesite (Sb₂O₃) and palaezoite (Sb₄S₄). It is obtained as a byproduct of lead, copper and tin refining. The main reserves are in China, Libya, Russia and Bolivia. Antimony never appears free in nature: it is always combined with other elements in minerals.

History and origin of the name

Antimony has been known since antiquity; its name comes from Latin 'Antimony', which could derive from Arabic 'antam' or Greek 'anti' + 'monos' (against the good), in reference to its toxicity. There is no clear individual discovery: the metal and its compounds were used in antiquity by artists, medicine and tinners. Pure metallic antimony was isolated in the 18th century.

Applications and relevance of antimony

Uses of the element

Metallic antimony is used in Alloy, especially with lead, to increase hardness and mechanical resistance. It is also used in specialised electronic formulations, in the manufacture of printing types and in the cosmetics industry (which contain stable antimony compounds).

Uses of its compounds

Antimony trioxide is a key synergist in the manufacture of flame retardant materials, combining with halides. It is also used in the manufacture of batteries, high-performance electronics and some compounds for the electric vehicle headlamp industry.

Health, safety and environment

Biological role

Antimony is not essential for living things. Inorganic antimony compounds can be toxic in high doses, causing gastrointestinal irritation, kidney effects and blood changes. Exact toxicity depends on chemical form and dose, so industrial use requires strict control.

Safety

Metallic antimony is relatively stable, but inorganic compounds are toxic and can cause irritation of skin, eyes and respiratory system. Antimony must be handled with adequate ventilation, gloves and eye protection. Industrial waste is treated in appropriate safety facilities.

Environment

Antimony discharges can contaminate soils and surface waters, affecting aquatic life. Antimony does not degrade in the environment and its accumulation is a risk for ecosystems near industrial sources. Recycling processes of metals with antimony help reduce pollution and consumption of natural minerals.

Frequently asked questions about Antimony

What is antimony used for?

Antimony is used in metallic alloys, semiconductor materials and various industrial compounds. When added to certain alloys, it can increase hardness and modify mechanical properties, so it is used in specialised applications. Some of its compounds are also used as flame retardant additives in polyester materials, usually in combination with other substances. In addition, antimony has applications in batteries and electronics. Its usefulness depends largely on the chemical form in which it is incorporated into the final material.

What is the difference between metallic antimony and its compounds?

Elemental antimony is a solid with metallic appearance and semiconductor behaviour, while its compounds show very varied properties depending on the elements they are combined with and their chemical structure. Some compounds are used in flame retardant materials, others in electronic applications and others in specialised industrial processes. Therefore, it is not correct to attribute to all antimony compounds the same characteristics of the pure element. Chemical composition and oxidation state are important factors to understand its behaviour.

What semiconductor properties does antimony have?

Elemental antimony presents electronic properties intermediate between those of metals and conventional semiconductors. Its crystalline structure and electronic behaviour make it a subject of study in specialised materials and devices. In addition, antimony forms semiconductor compounds with elements such as indium and gallium, whose properties can be adjusted through composition. These materials are investigated for electronic, optoelectronic and thermoelectric applications. Although it is not the dominant semiconductor in industry, it contributes to the development of technologies with specific requirements.

Can antimony form thermoelectric materials?

Yes. Some compounds containing antimony present thermoelectric properties, that is, they can convert a temperature difference into electricity or use electric current to produce heating and cooling. An example is bismuth antimony telluride, used in certain thermoelectric modules. Performance depends on composition, crystal structure and the material's ability to transport charges and limit heat conduction. These properties allow the development of compact cooling systems and devices to exploit small thermal differences.

Why is antimony added to the lead of some batteries?

In certain alloys used in lead-acid batteries, antimony modifies the mechanical and electrochemical properties of the material. Its incorporation can improve the resistance and ease of manufacture of the grids that hold the active electrode material. It also affects behaviour during charging and water loss, so its proportion must be adjusted to the battery design. There are alternatives with lower antimony content, developed to respond to different performance and maintenance needs.

How is antimony used to improve metallic alloys?

Antimony can be incorporated into certain alloys to modify their hardness, mechanical resistance and behaviour during manufacturing. A known example are some lead alloys, where it contributes to obtaining components that are more rigid and resistant than those manufactured with pure lead. It is also used in specialised metal formulations where the material's response to loads or shape changes is important. The specific effect depends on the antimony concentration, the other elements present and the treatment applied to the alloy.

What function does antimony trioxide have in flame retardant materials?

Antimony trioxide is used as a synergist in certain formulated flame retardants, especially when combined with halogenated compounds. In those mixtures, it can favour chemical mechanisms that reduce the spread of combustion. It does not necessarily act as an effective retardant on its own, but as part of a system formulated to improve fire behaviour. Its performance depends on the polymer, other additives and test conditions. Therefore, industrial formulations are designed and evaluated for each specific application.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.