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862.200
[222] u0, +2
[Xe] 4f14 5d10 6s2 6p6RnRadon

Radon

Radon is a chemical element with symbol Rn and atomic number 86. It is a radioactive, colorless, odorless, tasteless noble gas, occurring naturally as a decay product of radium. Its most stable isotope, 222Rn, has a half-life of 3.8 days.

Identity

Atomic mass
[222] u
Category
Noble gases
Group
18
Period
6
Block
p
Oxidation States
0, +2
Phase (25 °C)
Gas
Appearance
colorless gas, occasionally glows green or red in discharge tubes

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6
Short configuration
[Xe] 4f14 5d10 6s2 6p6
Electrons per shell
2, 8, 18, 32, 18, 8
Electronegativity (Pauling)
2.20
Electron affinity
-68 kJ/mol
1st ionization energy
1037 kJ/mol

Physical properties

Melting point
-71.1 °C (202 K)
Boiling point
-61.6 °C (212 K)
Density
0.00973 g/cm³
Molar heat capacity
—

Chemical behavior of radon

Radon is a radioactive noble gas of group 18 with symbol Rn and atomic number 86. It is the heaviest chemical element among the stable noble gases (except radioactive isotopes). It is a colourless, odourless and extremely toxic gas due to its radioactivity. Radon is the product of radioactive decay of uranium-238, thorium-232 and actinium-235, and decays by emitting alpha particles.

Reactivity

  • Rn does not form stable compounds

    Although radon is a noble gas, its radioactive instability and electron configuration make compound formation extremely limited and impractical.

  • Rn does not chemically react

    Radon has chemical properties similar to other noble gases in its period, with very low reactivity due to its complete valence shell.

Notable compounds

CompoundFormulaUse or importance
Radon oxideRnO₃ (theoretical)Hypothetical compound; does not exist stably due to radon's rapid decay
Radon hydrideRnH₂ (theoretical)Hypothetical compound; radon's short life prevents experimental observation

Electron shell distribution

Electron shell distribution diagram of Radon.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.RnView in the atom builder

Isotopes

Radon has 37 known isotopes, all radioactive. The most important is radon-222 (²²²Rn), with a half-life of 3.8 days, belonging to the uranium-238 decay chain. Radon-220, known as thoron, has a half-life of 55 seconds (thorium series). Radon-219, called actinon, is part of the actinium series. Radon-222 is the most abundant and its use predominates in most applications.

Occurrence and production

Radon is found in the Earth's crust as a byproduct of the radioactive decay of uranium, thorium and actinium present in rocks and soils. It appears in higher concentrations in regions with uranium-rich rocks, such as granites, felsites and certain minerals. Areas with groundwater, groundwater and caves tend to have higher radon levels due to continuous gas release.

History and origin of the name

Radon was discovered in 1899 by Ernest Rutherford and Robert B. Owens in the UK while studying the decay of Radium. They identified it as an invisible radioactive gas that remained in the air after the disappearance of radium. In 1900, Friedrich Ernst Dorn independently discovered the same gas in the decay of thorium. The name originated from the Latin word 'radius', meaning 'ray' or 'ray of light', in reference to its radioactive property.

Applications and relevance of radon

Uses of the element

Radon is used mainly in scientific research: geology studies, rock dating, tracing underground flows, and as an indicator of fractures and geological permeability in civil engineering and petroleum.

Uses of its compounds

Radon compounds are not stable and cannot be studied due to the radioactive nature and short life of radon. All its chemistry is based on theoretical hypotheses about its behaviour as a group 18 element.

Health, safety and environment

Biological role

Radon is highly radioactive and is considered a carcinogen linked to lung cancer. Its radioactivity causes damage to lung tissue by irradiating the walls of bronchi and alveoli when the gas is stored in rooms or closed spaces. High concentrations increase the risk of lung cancer, especially in smokers. The risk depends on concentration, duration of exposure and the person's health habits.

Safety

Radon is a colourless, odourless radioactive gas. Monitoring of its concentrations indoors is required to prevent dangerous exposures. Detection is carried out by particle counting equipment and air sample analysis methods. Spaces with high concentrations must be adequately ventilated and, if necessary, subjected to concentration reduction techniques. Radioactive waste must be handled in specialised facilities.

Environment

Radon is a natural component of the terrestrial environment. Its presence in soil does not constitute artificial pollution, but is part of the radioactive cycle of the Earth's crust. Industrial discharges of uranium and thorium can increase radon concentration in nearby regions. Handling of groundwater and natural gas containing radon requires specialised techniques to avoid protecting populations and ecosystems.

Frequently asked questions about Radon

How does radon help to study rock fractures?

Radon can move from the minerals where it is formed towards the pores and fractures of rocks. That is why measurements of its concentration can provide information about the circulation of gases and fluids in the subsurface. Researchers study these variations to understand the permeability of geological materials and changes in subterranean transport. However, the signal also depends on humidity, pressure, temperature and other factors, so it does not allow identifying a single fracture in isolation.

What is the difference between radon-222 and other radon isotopes?

Radon has several radioactive isotopes, but their half-lives and decay chains are different. Radon-222, belonging to the uranium-238 series, has a half-life of about 3.8 days. Other isotopes, such as radon-220, known as thoron, last much less. These differences determine how far they can move before decaying and in what contexts they can be detected. Therefore, identifying the isotope is important when interpreting geological and environmental measurements.

Why can radon move from soil to buildings?

Radon present in the ground can move through pores, cracks and spaces between building materials. Pressure differences between the ground and the inside of a building can favour its entry through joints, conduits or cracks in foundations. The ease of movement depends on the permeability of the ground, construction characteristics and ventilation. This process explains why two nearby buildings can have very different concentrations, even when built on the same type of ground.

Why is radon useful for studying groundwater circulation?

Radon can accumulate in groundwater when it comes into contact with minerals and materials that release it. When that water reaches rivers, lakes or coastal areas, the radon concentration can change and serve as an indication of groundwater inputs. Researchers use these variations to study water exchanges that are not always visible on the surface. The method requires comparing the concentrations with other indicators and considering radioactive decay, mixing and gas loss to the atmosphere.

Why is radon used as a tracer in environmental studies?

Radon can be used as a natural tracer to investigate gas exchange between soil, water and atmosphere. Its concentration and distribution help to study processes such as soil ventilation, groundwater circulation and certain exchanges between oceans and air. As it is radioactive, its temporal changes also provide information about the transport and renewal of water or air masses. Interpretation requires considering environmental conditions and the decay of the isotope itself.

How is radon detected if it is an invisible gas?

Radon cannot be identified by the naked eye, so it is measured by instruments that detect its radioactivity or that of its decay products. Some devices record alpha particles, while others use electronic detectors or air sample analysis methods. There are equipment for continuous measurements and others designed to obtain averages over long periods. The choice depends on the purpose of the study, the necessary sensitivity and sampling conditions. Results must be interpreted by knowing the limitations of each technique.

What is the relationship between radon and geological dating?

Radon is part of radioactive decay chains that include uranium and thorium isotopes. Its mobility and short half-life can provide information about recent geological processes, although it is not usually the main clock for determining the age of ancient rocks. In specialised research, the imbalances between isotopes in a radioactive chain help study the transport of elements and the evolution of natural systems. Interpretation requires knowing the production, migration and decay rates of the radionuclides involved.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.