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591.130
140.908 u+3, +4
[Xe] 4f3 6s2PrPraseodymium

Praseodymium

Praseodymium is a chemical element with symbol Pr and atomic number 59. Praseodymium is a soft, silvery, malleable and ductile metal in the lanthanide group. It is valued for its magnetic, electrical, chemical, and optical properties.

Identity

Atomic mass
140.908 u
Category
Lanthanides
Group
3
Period
6
Block
f
Oxidation States
+3, +4
Phase (25 °C)
Solid
Appearance
grayish white

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f3
Short configuration
[Xe] 4f3 6s2
Electrons per shell
2, 8, 18, 21, 8, 2
Electronegativity (Pauling)
1.13
Electron affinity
93 kJ/mol
1st ionization energy
527 kJ/mol
Ionization energies
527 · 1020 · 2086 · 3761 · 5551 kJ/mol

Physical properties

Melting point
934.9 °C (1208 K)
Boiling point
3129.8 °C (3403 K)
Density
6.77 g/cm³
Molar heat capacity
27.2 J/(mol·K)

Chemical behavior of praseodymium

Praseodymium has five outer electrons ([Xe] 4f³ 6s²) and almost always acts as +3, with a rare +4 in the oxide PrO₂ and in some salts. Its electronegativity is very low (1.13) and it forms highly ionic bonds. It is soft, malleable and oxidizes in air forming a green oxide layer that flakes off. Its Pr³⁺ ions are responsible for yellow and green colors and for an intense magnetism.

Reactivity

  • 4 Pr + 3 O₂ → 2 Pr₂O₃

    In air it becomes covered with a green oxide that does not protect the metal, so corrosion advances. When heated it burns to oxides, a mixture of Pr₂O₃ and PrO₂.

  • 2 Pr + 6 H₂O → 2 Pr(OH)₃ + 3 H₂

    It reacts with water more vigorously than cerium, giving hydroxide and hydrogen. The reaction speeds up when hot.

  • 2 Pr + 6 HCl → 2 PrCl₃ + 3 H₂

    It dissolves readily in dilute acids forming green praseodymium(III) salts, the starting point for magnets and glasses.

  • 2 Pr + 3 H₂ → 2 PrH₃

    With hydrogen it forms non-stoichiometric hydrides that absorb and release H₂. This is the chemistry that alloys exploit for batteries and storage.

Notable compounds

CompoundFormulaUse or importance
Praseodymium oxidePr₆O₁₁Yellow pigments and catalysts
Praseodymium fluoridePrF₃Laser crystals and optical fiber
Praseodymium chloridePrCl₃Production of the metal and magnets
Didymium glassPr-NdWelder's goggles and glassblowers' glasses
Pr-Fe-B alloyPr₂Fe₁₄BHigh-temperature permanent magnets

Electron shell distribution

Electron shell distribution diagram of Praseodymium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.PrView in the atom builder

Isotopes

All natural praseodymium is praseodymium-141 (¹⁴¹Pr), with 82 neutrons: it is monoisotopic and stable. The other known isotopes are artificial and short-lived. Its atomic mass therefore matches that of its only natural isotope.

Occurrence and production

It occurs at about 9 ppm in the crust, always in bastnasite and monazite alongside cerium, lanthanum and neodymium. It does not exist free or as a mineral of its own. It is obtained by acid dissolution of the ore and separation by solvent extraction and ion exchange, and the metal by electrolysis of molten chlorides or reduction with calcium.

History and origin of the name

Carl Auer von Welsbach separated it in 1885 from the supposed element didymium and named it praseodymium, from the Greek prasios (green) and didymos (twin), for the green colour of its salts and for being the twin of neodymium. Didymium had been considered an element for decades. Its separation confirmed that the rare earths hid almost identical pairs.

Applications and relevance of praseodymium

Uses of the element

As a metal it is alloyed with neodymium in high-temperature permanent magnets for electric motors, wind turbines and hard drives, and with magnesium in lightweight alloys for aircraft. It also goes into the mischmetal of lighters and into electrodes for batteries.

Uses of its compounds

Its oxides colour ceramics and enamels yellow and filter the yellow sodium light in welders' goggles and glassblowers' glasses. The fluoride dopes laser crystals, and the mixed oxide with cerium catalyses exhaust treatment and fuel cells.

Health, safety and environment

Biological role

It has no known biological function and is barely absorbed. There is no routine exposure from magnets, glasses or ceramics, where it is immobilized in stable matrices.

Safety

Fine metal powder can ignite and must be handled under an inert atmosphere with extraction and respiratory protection. Powerful magnets containing it present a mechanical hazard from entrapment and from ingestion of small pieces by children.

Environment

It shares the mining footprint of the rare earths: energy consumption in separation and waste with associated thorium. Its use in efficient motors and wind power saves emissions over the service life, and magnet recycling is beginning to recover high-value praseodymium.

Frequently asked questions about Praseodymium

What is praseodymium used for in magnets?

Praseodymium is used as a partial substitute for neodymium in neodymium-iron-boron magnets, among the most powerful permanent magnets available. Its addition can improve resistance to demagnetization and the magnet's behavior at elevated temperatures. These magnets are used in electric motors, wind turbines, hard drives, speakers and electronic devices. In this way, praseodymium helps sustain the performance of technologies that require intense, stable magnetic fields.

Is praseodymium dangerous to people?

Praseodymium does not occur freely in everyday life, and handling it as a metal or powder belongs to controlled industrial settings. As a fine powder it can be flammable and its inhalation should be avoided, but finished products —magnets, glasses, ceramics or alloys— do not normally release praseodymium to the user. There is no significant routine exposure for the general public. The relevant risks are associated with professional handling of powders, compounds or materials without adequate protection.

Is praseodymium really rare?

Although it belongs to the so-called rare earths, praseodymium is not extremely scarce in the Earth's crust. The term refers to its membership of a group of metals that usually occur together, at low concentrations within the same mineral, and that are difficult to separate. Practical scarcity depends more on the existence of exploitable deposits, technological demand and refining capacity than on the total amount existing on the planet.

What color does praseodymium produce in glass and ceramics?

Praseodymium compounds can give yellow, green or yellowish-green tones depending on the material and the manufacturing conditions. It is used to color decorative glasses, enamels, ceramics and certain types of technical glass. In welder's goggles, that same optical behavior is exploited to absorb annoying radiation. Praseodymium's ability to modify light makes it a valuable resource for both aesthetics and visual protection and optical instrumentation.

Why is praseodymium used in welder's glasses?

Praseodymium compounds selectively filter part of the yellow light and other intense radiation emitted during welding and glassblowing. That is why it is added to protective glasses that reduce glare without darkening vision completely. This ability to absorb specific wavelengths is also exploited in technical glasses and in the coloring of ceramics and glassware. It is an application based on its optical, not magnetic, properties.

Where does praseodymium come from?

Praseodymium is extracted from rare-earth minerals, especially bastnasite and monazite, where it appears mixed with cerium, neodymium and other lanthanides. After the ore is processed, solvent-extraction and ion-exchange techniques are used to separate it at high purity. It is rarely found as a native metal, but as compounds. Its production is complex because the lanthanides have very similar chemical properties and require highly precise separation processes.

What is the difference between praseodymium and neodymium?

Both are neighbouring lanthanides and are used in high-performance magnets, but neodymium is far better known for forming the basis of NdFeB magnets. Praseodymium can partially replace neodymium in those alloys and helps improve certain thermal and magnetic properties. In addition, praseodymium stands out for its optical applications, such as coloring and light filtering in protective glasses. In short: neodymium dominates commercial magnets; praseodymium complements that role and adds specialized uses.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.