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30.980
[6.938, 6.997] u+1
[He] 2s1LiLithium

Lithium

Lithium (from Greek:λίθος lithos, "stone") is a chemical element with the symbol Li and atomic number 3. It is a soft, silver-white metal belonging to the alkali metal group of chemical elements. Under standard conditions it is the lightest metal and the least dense solid element.

Identity

Atomic mass
[6.938, 6.997] u
Category
Alkali metals
Group
1
Period
2
Block
s
Oxidation States
+1
Phase (25 °C)
Solid
Appearance
silvery-white

Electronic Structure

Electron configuration
1s2 2s1
Short configuration
[He] 2s1
Electrons per shell
2, 1
Electronegativity (Pauling)
0.980
Electron affinity
59.6 kJ/mol
1st ionization energy
520 kJ/mol
Ionization energies
520 · 7298 · 11815 kJ/mol

Physical properties

Melting point
180.5 °C (454 K)
Boiling point
1341.8 °C (1615 K)
Density
0.534 g/cm³
Molar heat capacity
24.9 J/(mol·K)

Chemical behavior of lithium

Lithium has a single valence electron ([He] 2s¹) that it readily cedes to form the Li⁺ cation, with noble gas configuration. It is the lightest and least reactive of the alkali metals, and forms predominantly ionic bonds. Its small size gives it a high charge density: it polarizes anions and shows some covalent character, with diagonal similarities to magnesium. As an exception within its group, it reacts directly with nitrogen and does not form superoxides.

Reactivity

  • 2 Li + 2 H₂O → 2 LiOH + H₂

    Reacts with water releasing hydrogen, with vigor but without melting or inflaming like sodium, being the least reactive alkali metal. It floats and moves across the surface as it dissolves.

  • 4 Li + O₂ → 2 Li₂O

    With oxygen it forms exclusively the normal oxide, unlike its congeners that give peroxides and superoxides. The reaction is slow at room temperature and rapid when heated.

  • 6 Li + N₂ → 2 Li₃N

    It is the only alkali metal that reacts directly with nitrogen forming a nitride, even at room temperature. This singularity brings it close to magnesium through diagonal relationship.

  • 2 Li + H₂ → 2 LiH

    When heated it forms lithium hydride, a saline solid used as a reducing agent and as a hydrogen source, since it releases H₂ on contact with water.

Notable compounds

CompoundFormulaUse or importance
Lithium carbonateLi₂CO₃Precursor of battery materials; glass, ceramic and mood-stabilizing drug
Lithium hydroxideLiOHCO₂ absorption in submarines and ships; lubricating greases
Lithium chlorideLiClMolten salts, dehumidifiers and pyrotechnics
Lithium hydrideLiHReducing agent and chemical hydrogen accumulator
Lithium cobalt oxideLiCoO₂Cathode material in lithium-ion batteries

Electron shell distribution

Electron shell distribution diagram of Lithium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.LiView in the atom builder

Isotopes

Natural lithium combines two stable isotopes: lithium-7 (⁷Li), with four neutrons and 92.5 %, and lithium-6 (⁶Li), with three neutrons and 7.5 %. Lithium-6 is strategic: bombarded with neutrons it generates tritium for nuclear fusion, and both isotopes are used in magnetic resonance imaging and dating.

Occurrence and production

It is a relatively scarce metal (about 20 ppm of the crust) that never appears free. Its sources are the brines of the Andean salt flats —the "lithium triangle" of Chile, Argentina and Bolivia—, the spodumene pegmatites of Australia and some clays. It is obtained by solar evaporation and precipitation as carbonate, or by roasting and leaching of spodumene.

History and origin of the name

Johan August Arfwedson discovered it in 1817 analyzing petalite, and Jöns Berzelius named it lithium, from lithos (stone), for being found in minerals. Davy and Brande isolated the first impure metallic samples, and in 1855 Bunsen and Matthiessen obtained it pure by electrolysis of molten chloride.

Applications and relevance of lithium

Uses of the element

Its major application is energy storage: lithium-ion batteries power mobiles, laptops and electric cars thanks to their lightness and electrochemical potential. It also hardens aluminum alloys for aerospace and thickens lithium lubricating greases.

Uses of its compounds

Carbonate feeds the glass, ceramic and bipolar disorder drug industries; hydroxide absorbs CO₂ and prepares cathodes; chloride is used in molten salts, dehumidifiers and pyrotechnics; hydride is a reducing agent and hydrogen accumulator; lithium cobalt oxide is the cathode material of lithium-ion batteries.

Health, safety and environment

Biological role

The lithium ion, in carbonate form, is used as a mood stabilizer in bipolar disorder treatment. However, the margin between effective and toxic dose is narrow, requiring periodic blood tests, kidney function monitoring and constant medical supervision.

Safety

Lithium metal is flammable and reacts with water, releasing hydrogen. It must be handled with appropriate precautions and stored under inert liquid such as mineral oil or kerosene. It should not be handled with bare hands.

Environment

Lithium extraction from salt flats generates debate over water consumption in one of the planet's most arid deserts. Battery recycling, still a minority practice, is key to reducing extraction and closing the lithium cycle.

Frequently asked questions about Lithium

Why does lithium dominate rechargeable batteries?

Because it combines three unique advantages: it is the lightest metal, it cedes its electron easily, and its tiny ions move quickly between electrodes. This gives batteries with high energy per kilogram and thousands of charge cycles. No other element combines so much lightness and electrochemical potential at once, although sodium is starting to compete in cheap stationary applications.

Is it true that lithium is used as medication?

Yes. Lithium salts, especially carbonate, stabilize mood in bipolar disorder and reduce the risk of relapses and suicide for more than half a century. But the margin between effective and toxic dose is narrow, so treatment requires periodic blood tests, kidney function control and constant medical supervision. Nothing to do with battery lithium: no one should self-medicate.

Can lithium from batteries be recycled?

Yes, and it is increasingly profitable: spent batteries are crushed and lithium is recovered by hydrometallurgical processes together with cobalt, nickel and copper. Today only a small fraction is recycled because most batteries are still in use, collection fails and many end up stored in drawers. With millions of electric cars retiring in the next decade, recycling will be a true essential "urban mine".

Why does lithium float in water if it reacts with it?

Because it is the least dense metal that exists (0.534 g/cm³): it floats even in mineral oil where it is stored. On contact with water it reacts releasing hydrogen, but with less violence than sodium or potassium, without melting or burning. It moves across the surface effervescing and bubbling until it dissolves completely as lithium hydroxide, a reaction that is spectacular but controllable.

What is the "lithium triangle"?

It is the Andean region where Argentina, Bolivia and Chile converge, whose salt flats concentrate more than half of the world's lithium resources in brine. Salty groundwater is pumped to large solar evaporation ponds, where sun and wind concentrate it for months until salts precipitate. Its exploitation generates debate over water consumption in one of the planet's most arid deserts.

How does lithium differ from sodium and potassium?

It is the least reactive alkali metal: it attacks water without inflaming and only forms the normal oxide, never peroxides or superoxides like its siblings. Its tiny ion, with high charge density, polarizes anions and gives it a covalent air that recalls magnesium (diagonal relationship). In addition, it is the only one of the group that forms nitride directly with nitrogen (Li₃N). In return, it is more expensive and scarcer than sodium or potassium.

Will lithium run out with electric cars?

Not in the short term: identified resources exceed 100 million tonnes and grow each year with new prospecting in salt flats, pegmatites and clays. The bottleneck is the pace of mine and refinery opening, concentrated in few countries. In the long term, massive battery recycling and emerging alternatives such as sodium batteries will alleviate pressure on this strategic metal.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.