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322.010
72.63 u−4, +2, +4
[Ar] 3d10 4s2 4p2GeGermanium

Germanium

Germanium is a chemical element with symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. Purified germanium is a semiconductor, with an appearance most similar to elemental silicon.

Identity

Atomic mass
72.63 u
Category
Metalloids
Group
14
Period
4
Block
p
Oxidation States
−4, +2, +4
Phase (25 °C)
Solid
Appearance
grayish-white

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p2
Short configuration
[Ar] 3d10 4s2 4p2
Electrons per shell
2, 8, 18, 4
Electronegativity (Pauling)
2.01
Electron affinity
119 kJ/mol
1st ionization energy
762 kJ/mol
Ionization energies
762 · 1538 · 3302 · 4411 · 9020 kJ/mol

Physical properties

Melting point
938.3 °C (1211 K)
Boiling point
2832.8 °C (3106 K)
Density
5.323 g/cm³
Molar heat capacity
23.2 J/(mol·K)

Chemical behavior of germanium

Germanium is a metalloid of group 14 that presents the oxidation states +2 and +4, +4 being the most stable and most frequent in its chemistry. Its electronegativity of 2.01 (Pauling scale) gives it some ability to accept electrons without reaching a strong non-metal character. Its predominant bond is covalent, both in pure element and in its compounds, with a tendency to form four bonds directed tetrahedrally. Exceptions: unlike silicon or carbon, germanium can also show oxidation state +2 in compounds such as germanium(II) chloride (GeCl₂), although it is less stable and tends to disproportionate towards +4.

Reactivity

  • Ge + 2 Cl2 -> GeCl4

    Metallic germanium reacts with chlorine at high temperature to give germanium(IV) chloride, a colourless volatile liquid that is the usual chemical precursor in the manufacture of special oxides and glasses.

  • Ge + 2 O2 -> GeO2

    Heating germanium in air forms germanium dioxide, a white amphoteric solid that reacts with both strong acids and concentrated bases, depending on the medium.

  • GeO2 + 4 HCl -> GeCl4 + 2 H2O

    Germanium dioxide dissolves in strong hydrochloric acid, evidencing its amphoteric character: acts as an acidic oxide in basic medium and as basic in acidic medium.

Notable compounds

CompoundFormulaUse or importance
Germanium tetrachlorideGeCl4Volatile liquid precursor of oxides and special glasses; basis of semiconductor chemistry
Germanium dioxideGeO2Key reagent in the manufacture of optical fibres and high-temperature ceramic materials
Germanium(IV) sulfideGeS2Yellow solid that appears in germanium minerals; source mineral feedstock
Sodium germanateNa2GeO3Water-soluble salt; used in industrial manufacturing processes

Electron shell distribution

Electron shell distribution diagram of Germanium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.GeView in the atom builder

Isotopes

Natural germanium is composed of five stable: germanium-70 (⁷⁰Ge, 20.5%), germanium-72 (⁷²Ge, 27.4%), germanium-73 (⁷³Ge, 7.8%, which captures neutrons and is useful in detectors), germanium-74 (⁷⁴Ge, 36.5%) and germanium-76 (⁷⁶Ge, 7.8%, which presents double beta decay with extremely long period). The most abundant is ⁷⁴Ge. There are no environmentally relevant radioactive isotopes; ⁷⁶Ge is slightly radioactive, but its half-life exceeds 10²¹ years, so its activity is so minimal that it does not influence any measurable property.

Occurrence and production

Germanium is a relatively scarce element, with a concentration in the Earth's crust of about 1.5 ppm. It occurs mainly combined in minerals such as arfvedita (GeS₂) and germanite (GeO₂), although high-concentration reserves are scarce. Most of the germanium is obtained as a byproduct of copper, tin and lead mining, as well as from coal ashes. The production process includes dissolution in acids, controlled precipitation and GeCl₄ distillation to obtain very pure metal.

History and origin of the name

Germanium was discovered by the German chemist Clemens Winkler in 1886, at a time when the Dmitri Mendeleev of Dimitri Mendeleyev of an element 'ekasilicon' was one of the strongest validations of the periodic system. Winkler isolated it from arfvedita from the Freyberg mine (Saxony, Germany), and its name derives from Latin 'Germania' in honour of the country of its discovery.

Applications and relevance of germanium

Uses of the element

Metallic germanium is used as a dopant in silicon to manufacture transistors, diodes and optoelectronic components. Its Semiconductor is exploited in high-frequency devices and in the manufacture of high-efficiency photovoltaic panels.

Uses of its compounds

Germanium dioxide is the basis of modern optical fibres, allowing light to be guided with very little loss. It is also used in gamma radiation detectors, detection systems, advanced OLEDs, and galvanisation to protect metals from corrosion.

Health, safety and environment

Biological role

Germanium is not essential for living things. There is no clear evidence of biological function; organic germanium compounds have been studied as possible immune modulators, but without approving their health use without reservations.

Safety

Germanium inorganic substances can be irritating and toxic at high doses. Germanium tetrachloride is corrosive and reacts violently with water releasing hydrochloric acid, so it requires handling in sealed and well-ventilated areas.

Environment

Germanium discharges are uncommon and strictly controlled by hazardous waste regulations. Metallic germanium is stable and does not react dangerously with the environment; the main environmental risk comes from water-soluble compounds.

Frequently asked questions about Germanium

What is germanium used for?

Germanium is used in specialised electronic, optical and technological applications. Its semiconductor properties allow it to be incorporated into certain electronic devices, while its refraction index and behaviour against infrared radiation make it valuable for manufacturing optical components. It is also used in some high-performance solar cells and in materials for optical fibre. Although silicon dominates much of conventional electronics, germanium remains important when its specific properties offer technological advantages.

What is the difference between germanium and silicon?

Germanium and silicon are semiconductors of the same group of the periodic table, but they have different electronic properties. Germanium has a narrower bandgap, which modifies its electrical and optical response, especially at room temperature. This can favour certain high-speed or detection applications, although it can also increase unwanted currents in certain devices. Silicon, on the other hand, offers advantages of cost, technological availability and the formation of a very useful oxide for manufacturing integrated circuits.

Why is germanium used in some solar cells?

Germanium can act as a semiconductor material in specialised solar cells, especially in multijunction devices used in space applications. These cells combine several semiconductor layers that absorb different regions of the solar spectrum, making better use of the light energy than a conventional unit. Germanium can serve as a substrate and participate in the structure of certain cells. Its choice depends on factors such as performance, weight, cost and expected operating conditions of the photovoltaic system.

Can germanium be used in radiation detectors?

Yes. Highly pure germanium is used in semiconductor detectors capable of measuring the energy of gamma radiation with excellent energy resolution. When radiation interacts with the material, it generates electric charges whose signal allows estimating the deposited energy. These detectors are used in nuclear research, material analysis and specialised environmental measurements. For proper operation, many systems of highly pure germanium require refrigeration, which reduces electrical noise and improves the quality of recorded signals.

Why is germanium used in infrared cameras?

Germanium presents high transmission of certain infrared wavelengths, especially in regions used for obtaining thermal images. For this reason, it is used in lenses, windows and other optical components of infrared cameras and thermal vision systems. Its high refraction index also influences lens design. However, its transmission depends on the wavelength, purity and surface treatment, so it is not suitable for any optical application.

How is germanium used in optical fibre?

In the manufacture of certain optical fibres, small amounts of germanium are incorporated into silica to modify its refraction index. This variation allows creating a central region through which light is guided along the fibre. Control of composition and refraction index profile is essential to obtain the desired optical properties. Thanks to this technique, fibres can transport light signals over great distances and form part of modern telecommunications infrastructures.

What electronic properties make germanium interesting?

Germanium is a semiconductor with a relatively narrow bandgap and carrier mobility that can be favourable in certain devices. These characteristics allow studying and developing electronic components that take advantage of its response to electric fields and high-frequency signals. However, its behaviour also depends on temperature, impurities and crystal defects. Therefore, although it offers advantages in some specialised applications, it does not automatically replace silicon, whose properties and manufacturing processes are optimised for a huge variety of circuits.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.