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261.830
55.845 u+2, +3
[Ar] 3d6 4s2FeIron

Iron

Iron is a chemical element with symbol Fe (from Latin:ferrum) and atomic number 26. It is a metal in the first transition series. It is by mass the most common element on Earth, forming much of Earth's outer and inner core.

Identity

Atomic mass
55.845 u
Category
Transition metals
Group
8
Period
4
Block
d
Oxidation States
+2, +3
Phase (25 °C)
Solid
Appearance
lustrous metallic with a grayish tinge

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d6
Short configuration
[Ar] 3d6 4s2
Electrons per shell
2, 8, 14, 2
Electronegativity (Pauling)
1.83
Electron affinity
14.8 kJ/mol
1st ionization energy
763 kJ/mol
Ionization energies
763 · 1562 · 2957 · 5290 · 7240… kJ/mol

Physical properties

Melting point
1537.8 °C (1811 K)
Boiling point
2860.8 °C (3134 K)
Density
7.874 g/cm³
Molar heat capacity
25.1 J/(mol·K)

Chemical behavior of iron

Iron is a transition metal of group 8 with symbol Fe and atomic number 26. It is one of the most abundant metals in the Earth's crust and one of the most used by humans. It is a soft metal with greyish silver metallic lustre, magnetic and with excellent mechanical properties. It presents main oxidation states +2 and +3, with +3 being the most stable. It is fundamental both for industry and for biological processes.

Reactivity

  • 2 Fe + 3 Cl₂ → 2 FeCl₃

    Iron reacts with chlorine to form iron(III) chloride, a brown solid that is the most stable compound.

  • Fe + H₂SO₄ (hot) → FeSO₄ + H₂

    Iron reacts with hot sulfuric acid, releasing hydrogen and forming iron(II) sulfate.

Notable compounds

CompoundFormulaUse or importance
Iron(III) oxideFe₂O₃Brown solid; used as pigment, in welding and in chemical reagents
Iron(II) dichlorideFeCl₂Green solid; precursor of getter and reduction agent
Iron(III) sulfateFe₂(SO₄)₃Brown solid; used in water treatment and as analytical reagent

Electron shell distribution

Electron shell distribution diagram of Iron.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.FeView in the atom builder

Isotopes

Natural iron is composed of four stable isotopes: iron-54 (⁵⁴Fe, 5.85%), iron-56 (⁵⁶Fe, 91.75%), iron-57 (⁵⁷Fe, 2.12%) and iron-58 (⁵⁸Fe, 0.28%). Iron-56 is the most abundant. There are also radioactive isotopes of iron, with the most stable being iron-52 with a half-life of 8.3 hours.

Occurrence and production

Iron is the fourth most abundant element in the Earth's crust, with concentrations of 5% by mass. It appears in minerals such as Hematite (Fe₂O₃), magnetite (Fe₃O₄) and siderite (FeCO₃). The main reserves are in Australia, Brazil, China, India, Russia and the United States. It is obtained mainly by iron ore casting.

History and origin of the name

Iron has been used by humans since the Iron Age, approximately 3,000 years ago. The first records of its use come from ancient Mesopotamia and Egypt. The name derives from Anglo-Saxon, while the symbol Fe comes from Latin 'ferrum'. Until the 19th century there were no efficient methods of melting iron; the Bessemer process revolutionised its production from 1856.

Applications and relevance of iron

Uses of the element

Iron is used mainly in steels and alloys, as structural materials in construction, in the automotive industry, in manufacturing and in the creation of tools. It is also used in the production of stainless steel and in industrial processes.

Uses of its compounds

Iron is used in various compounds: silica sand and aluminium combine with iron to produce ceramics, paints, red pigments, fertilisers and chemical reagents. Iron(III) sulfate is used in sanitary installations, water treatment and as precipitant in the teck industry.

Health, safety and environment

Biological role

Iron is essential for all living organisms. It is part of haemoglobin, the protein of red blood cells that transports oxygen, and in muscle myoglobin. It also participates in numerous enzymes and metabolic processes. Iron deficiency is one of the most common causes of anaemia in the world, while overload can cause hepatitis, diabetes and liver disease.

Safety

Iron metal is relatively stable and not toxic. Fine iron particles can irritate skin and eyes, and its prolonged inhalation can cause respiratory irritation. Iron deficiency is a common problem because the main sign is anaemia. It is recommended to handle with care and maintain adequate iron levels in the diet.

Environment

Iron is an abundant metal and its presence in soil and water influences ecosystems. However, the sediment of iron oxide can contaminate waters and affect aquatic life. Proper handling of mining waste and reduction of industrial emissions are important to prevent environmental contamination related to iron.

Frequently asked questions about Iron

Why is iron used as a catalyst in the manufacture of ammonia?

Iron is the main catalyst of the Haber-Bosch process, used industrially to produce ammonia from nitrogen and hydrogen. Its surface facilitates the breaking of the bonds of nitrogen molecules and favours the formation of new bonds with hydrogen. The reaction is carried out at high pressure and controlled temperature, with a catalytic formulation designed to maintain sufficient activity. The ammonia obtained is a fundamental raw material for making fertilisers and numerous chemical products.

Why is iron essential for transporting oxygen in blood?

Iron is part of the heme group of haemoglobin, the protein of red blood cells that transports oxygen from lungs to tissues. The iron atom allows haemoglobin to bind to oxygen reversibly, facilitating its capture and release during circulation. Iron also appears in muscle myoglobin and in enzymes involved in cellular processes. Its biological function depends on the organism maintaining adequate availability, as both deficiency and overload can have harmful consequences.

Why is iron important in electric motors and transformers?

Numerous motors and transformers use electrical steels containing iron and designed to respond adequately to variable magnetic fields. In transformers, these materials help concentrate magnetic flux and allow energy transfer between circuits. In motors, they contribute to generating the electromagnetic forces that produce motion. Steel composition and processing are controlled to reduce energy losses, such as those associated with hysteresis and induced currents, thereby improving equipment efficiency.

Why does iron oxidise and how can corrosion be avoided?

When iron is exposed to water and oxygen, electrochemical reactions can occur that originate oxides and hydroxides commonly known as rust. Corrosion can advance and weaken the material, especially in humid environments or with dissolved salts. To reduce it, coatings of paint, galvanisation with zinc, cathodic protection and alloys designed to better resist certain environments are used. The most appropriate solution depends on the use, environmental conditions and expected maintenance of the item.

What is the relationship between iron and magnetism?

Iron is one of the most well-known ferromagnetic materials. Under certain conditions, its internal magnetic regions can align and produce intense magnetisation. This behaviour allows the manufacture of electromagnets, transformer cores, electric motors and numerous magnetic devices. However, magnetic properties depend on the material's structure, its temperature and the treatments it has undergone. For example, when it exceeds its Curie temperature, iron loses its ferromagnetism and behaves differently in a magnetic field.

How is iron used to transform gases into liquid fuels?

Iron-based catalysts can be used in the Fischer-Tropsch process, which converts a mixture of carbon monoxide and hydrogen, known as synthesis gas, into hydrocarbons. These products can subsequently be processed to obtain fuels and other chemical raw materials. Iron favours the reactions that form bonds between carbon atoms, although product distribution depends on operating conditions and catalyst formulation. The technology can use synthesis gas from different raw materials.

What is the difference between cast iron and steel?

Cast iron and steel are iron and carbon-based materials, but differ mainly in carbon content and microstructure. In general, steel contains less carbon, while cast iron has a higher proportion, which favours its fluidity when moulded. This makes many cast irons suitable for making parts with complex geometries, such as chassis and engine blocks. Steel, on the other hand, offers a wide variety of combinations of strength, ductility and toughness.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.