Caesium or cesium is a chemical element with symbol Cs and atomic number 55. It is a soft, silvery-gold alkali metal with a melting point of 28 °C (82 °F), which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium is an alkali metal and has physical and chemical properties similar to those of rubidium and potassium.
Cesium has a single electron in the 6s orbital ([Xe] 6s¹), retained with infinitesimal electrostatic energy due to the voluminous atomic radius and the shielding effect of 54 internal electrons. It instantaneously cedes this electron to form the Cs⁺ cation with noble gas (xenon) electron configuration. It is the most electropositive, reactive and basic metal of all stable elements in the periodic table. It forms bonds with almost purely ionic character. It is an extremely soft metal of silvery-golden tone that melts at 28.5 °C, liquefying with the heat of the hand.
2 Cs + 2 H₂O → 2 CsOH + H₂
Reacts violently and explosively with liquid water and ice even at −116 °C, shattering the glass container and igniting the hydrogen generated instantly.
Cs + O₂ → CsO₂
Burns spontaneously on contact with air or oxygen forming dark orange cesium superoxide.
2 Cs + 2 H⁺ → 2 Cs⁺ + H₂
Attacks acids with undue and instantaneous violence, releasing hydrogen in an uncontrollable reaction.
2 Cs + Cl₂ → 2 CsCl
It combines livelily and explosively with chlorine and the other halogens giving ionic salts with body-centered cubic crystalline structure.
| Compound | Formula | Use or importance |
|---|---|---|
| Cesium formate | HCOOCs | Organic salt of unspeakable solubility used to prepare hyperdense and non-toxic petroleum drilling fluids |
| Cesium chloride | CsCl | Reference salt of cubic crystallographic structure; used in density gradient ultracentrifugation to separate DNA and viruses |
| Cesium hydroxide | CsOH | The strongest inorganic base known, capable of attacking and dissolving laboratory glass with great speed |
| Cesium iodide | CsI | Scintillating crystal in gamma radiation detectors, Fourier transform infrared spectroscopy (FTIR) and medical physics |
Natural cesium is exclusively monoisotopic, made up 100 % of the stable isotope cesium-133 (¹³³Cs, with 78 neutrons). Among its nearly forty artificial radioisotopes, cesium-137 (¹³⁷Cs, half-life of 30.17 years) is one of the most notorious nuclear fission products: it emits penetrating beta and gamma radiation, being a persistent environmental contaminant in nuclear accidents and a potent source of brachytherapy and industrial radiotherapy.
It is a scarce element in the Earth's crust (about 3 ppm). The main mineral from which it is exploited is pollucite (a hydrated cesium aluminosilicate, Cs(Si₂Al)O₆·nH₂O), whose largest world deposits are found at Bernic Lake in Manitoba (Canada), Zimbabwe and China. It is obtained by acid digestion of pollucite with hydrochloric or sulfuric acid, followed by precipitation as cesium alum and vacuum thermal reduction of molten cesium chloride with metallic calcium at 750 °C.
It was discovered in 1860 by German chemists Robert Bunsen and Gustav Kirchhoff in Bad Dürkheim mineral water using the flame spectroscope recently invented by them, constituting the first chemical element discovered by spectroscopy. In the optical spectrum they observed two extraordinarily bright and well-defined celestial blue lines. They called it "caesium" from the Latin adjective "caesius", a term used by the Romans to describe the light blue color of the sky or blue eyes.
Cesium is the base element of the International System of Units (SI): since 1967, the official definition of the physical second equals exactly 9,192,631,770 periods of the radiation associated with the transition between the two hyperfine levels of the ground state of the cesium-133 atom at rest. Cesium beam atomic clocks synchronize GPS satellites, global telecommunications and internet servers. It is also used in space ion thrusters and photovoltaic cells.
Cesium formate is a high-density fluid indispensable in high-pressure gas drilling wells in the North Sea. Cesium chloride is the standard salt in molecular DNA ultracentrifugation; and thallium-doped cesium iodide is the detector crystal in scanners and particle physics experiments.
Natural cesium does not fulfill any known physiological function. By sharing chemical properties with potassium, the Cs⁺ ion is easily absorbed by the gastrointestinal tract and distributed through animal muscle tissue, being slowly eliminated via the renal route without acute toxicity in natural trace doses.
Metallic cesium is extremely pyrophoric and dangerous: it ignites spontaneously in air and reacts with instantaneous explosiveness with any trace of water or moisture. It must be handled in vacuum-sealed borosilicate ampoules under ultrapure argon gas. Its thermal and chemical burns are fulminant.
The cesium-137 radioisotope released in Chernobyl or Fukushima is tenaciously fixed in soil clay minerals and is absorbed by mushrooms, berries and wild animals such as wild boars, persisting in forest trophic chains for decades.
Until the mid-20th century the second was measured with the Earth's rotation, which is not entirely constant. Since 1967, the official second is defined by measuring the internal vibration of the cesium-133 atom. When this atom receives specific microwaves, its electrons jump between two energy levels exactly 9,192,631,770 times in each second, serving as the master pattern for time around the planet.
When a concentrated cesium chloride solution is subjected to hundreds of thousands of gravities in an ultracentrifuge, cesium ions migrate to the bottom, creating a continuous and stable physical density gradient along the tube. Suspended DNA macromolecules move until they are placed exactly in the band where their own buoyant density matches that of the saline solution, allowing distinguishing heavy and light DNA strands in molecular biology.
In 1987, two scavengers looted an abandoned radiotherapy clinic in Goiânia (Brazil) and dismantled a teletherapy unit containing a capsule of cesium-137 chloride powder. Fascinated by the powder that glowed with a faint blue light in the darkness due to the Cherenkov effect, they showed it to family and neighbors. The dispersion of the radioactive powder contaminated hundreds of people, caused four immediate deaths and forced the demolition of homes and the burial of tons of nuclear debris.
Cesium was the pioneering propellant of space ion engines due to having the lowest ionization energy of stable elements (3.89 electronvolts) and a considerable atomic mass. By bringing cesium vapor into contact with a hot porous tungsten grid, cesium atoms spontaneously cede their electron to the metal and transform into positive ions. Electrostatic fields accelerate these ions to tremendous speeds toward outer space, generating a hyper-efficient continuous thrust.
Cesium has an exceptionally low melting point, only 28.5 °C. This means that on a hot summer day or holding a sealed glass ampoule in the palm of the hand, body heat melts the metal in a few minutes. In addition, it is one of the few metals with a beautiful pale golden luster, although it should never be touched directly due to its extreme reactivity.
Cesium formate is a monovalent organic salt with colossal water solubility, generating clear brines with densities of up to 2.3 grams per cubic centimeter without the need for suspended solid particles. In offshore oil and gas wells subjected to extreme pressures and temperatures (HPHT), this fluid lubricates the drill bit, balances the colossal reservoir pressure to prevent blowouts and does not damage the porous walls of the hydrocarbon-producing rock.
Cesium hydroxide (CsOH) combines the most voluminous and electropositive metallic cation of the periodic table with the hydroxide anion. The Cs-O bond is almost purely ionic, so in water it dissociates 100 % releasing hydroxide ions without any electrostatic restriction. This excessive basicity allows it to attack borosilicate glasses, corrode refractory ceramics and dissolve biological tissues with a thermal and chemical aggressiveness far superior to caustic soda or caustic potash.
Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.