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550.790
132.905 u+1
[Xe] 6s1CsCesium

Cesium

Caesium or cesium is a chemical element with symbol Cs and atomic number 55. It is a soft, silvery-gold alkali metal with a melting point of 28 °C (82 °F), which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium is an alkali metal and has physical and chemical properties similar to those of rubidium and potassium.

Identity

Atomic mass
132.905 u
Category
Alkali metals
Group
1
Period
6
Block
s
Oxidation States
+1
Phase (25 °C)
Solid
Appearance
silvery gold

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s1
Short configuration
[Xe] 6s1
Electrons per shell
2, 8, 18, 18, 8, 1
Electronegativity (Pauling)
0.790
Electron affinity
45.5 kJ/mol
1st ionization energy
376 kJ/mol
Ionization energies
376 · 2234 · 3400 kJ/mol

Physical properties

Melting point
28.6 °C (302 K)
Boiling point
670.9 °C (944 K)
Density
1.93 g/cm³
Molar heat capacity
32.2 J/(mol·K)

Chemical behavior of cesium

Cesium has a single electron in the 6s orbital ([Xe] 6s¹), retained with infinitesimal electrostatic energy due to the voluminous atomic radius and the shielding effect of 54 internal electrons. It instantaneously cedes this electron to form the Cs⁺ cation with noble gas (xenon) electron configuration. It is the most electropositive, reactive and basic metal of all stable elements in the periodic table. It forms bonds with almost purely ionic character. It is an extremely soft metal of silvery-golden tone that melts at 28.5 °C, liquefying with the heat of the hand.

Reactivity

  • 2 Cs + 2 H₂O → 2 CsOH + H₂

    Reacts violently and explosively with liquid water and ice even at −116 °C, shattering the glass container and igniting the hydrogen generated instantly.

  • Cs + O₂ → CsO₂

    Burns spontaneously on contact with air or oxygen forming dark orange cesium superoxide.

  • 2 Cs + 2 H⁺ → 2 Cs⁺ + H₂

    Attacks acids with undue and instantaneous violence, releasing hydrogen in an uncontrollable reaction.

  • 2 Cs + Cl₂ → 2 CsCl

    It combines livelily and explosively with chlorine and the other halogens giving ionic salts with body-centered cubic crystalline structure.

Notable compounds

CompoundFormulaUse or importance
Cesium formateHCOOCsOrganic salt of unspeakable solubility used to prepare hyperdense and non-toxic petroleum drilling fluids
Cesium chlorideCsClReference salt of cubic crystallographic structure; used in density gradient ultracentrifugation to separate DNA and viruses
Cesium hydroxideCsOHThe strongest inorganic base known, capable of attacking and dissolving laboratory glass with great speed
Cesium iodideCsIScintillating crystal in gamma radiation detectors, Fourier transform infrared spectroscopy (FTIR) and medical physics

Electron shell distribution

Electron shell distribution diagram of Cesium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.CsView in the atom builder

Isotopes

Natural cesium is exclusively monoisotopic, made up 100 % of the stable isotope cesium-133 (¹³³Cs, with 78 neutrons). Among its nearly forty artificial radioisotopes, cesium-137 (¹³⁷Cs, half-life of 30.17 years) is one of the most notorious nuclear fission products: it emits penetrating beta and gamma radiation, being a persistent environmental contaminant in nuclear accidents and a potent source of brachytherapy and industrial radiotherapy.

Occurrence and production

It is a scarce element in the Earth's crust (about 3 ppm). The main mineral from which it is exploited is pollucite (a hydrated cesium aluminosilicate, Cs(Si₂Al)O₆·nH₂O), whose largest world deposits are found at Bernic Lake in Manitoba (Canada), Zimbabwe and China. It is obtained by acid digestion of pollucite with hydrochloric or sulfuric acid, followed by precipitation as cesium alum and vacuum thermal reduction of molten cesium chloride with metallic calcium at 750 °C.

History and origin of the name

It was discovered in 1860 by German chemists Robert Bunsen and Gustav Kirchhoff in Bad Dürkheim mineral water using the flame spectroscope recently invented by them, constituting the first chemical element discovered by spectroscopy. In the optical spectrum they observed two extraordinarily bright and well-defined celestial blue lines. They called it "caesium" from the Latin adjective "caesius", a term used by the Romans to describe the light blue color of the sky or blue eyes.

Applications and relevance of cesium

Uses of the element

Cesium is the base element of the International System of Units (SI): since 1967, the official definition of the physical second equals exactly 9,192,631,770 periods of the radiation associated with the transition between the two hyperfine levels of the ground state of the cesium-133 atom at rest. Cesium beam atomic clocks synchronize GPS satellites, global telecommunications and internet servers. It is also used in space ion thrusters and photovoltaic cells.

Uses of its compounds

Cesium formate is a high-density fluid indispensable in high-pressure gas drilling wells in the North Sea. Cesium chloride is the standard salt in molecular DNA ultracentrifugation; and thallium-doped cesium iodide is the detector crystal in scanners and particle physics experiments.

Health, safety and environment

Biological role

Natural cesium does not fulfill any known physiological function. By sharing chemical properties with potassium, the Cs⁺ ion is easily absorbed by the gastrointestinal tract and distributed through animal muscle tissue, being slowly eliminated via the renal route without acute toxicity in natural trace doses.

Safety

Metallic cesium is extremely pyrophoric and dangerous: it ignites spontaneously in air and reacts with instantaneous explosiveness with any trace of water or moisture. It must be handled in vacuum-sealed borosilicate ampoules under ultrapure argon gas. Its thermal and chemical burns are fulminant.

Environment

The cesium-137 radioisotope released in Chernobyl or Fukushima is tenaciously fixed in soil clay minerals and is absorbed by mushrooms, berries and wild animals such as wild boars, persisting in forest trophic chains for decades.

Frequently asked questions about Cesium

How does cesium define the exact duration of a second?

Until the mid-20th century the second was measured with the Earth's rotation, which is not entirely constant. Since 1967, the official second is defined by measuring the internal vibration of the cesium-133 atom. When this atom receives specific microwaves, its electrons jump between two energy levels exactly 9,192,631,770 times in each second, serving as the master pattern for time around the planet.

How does cesium chloride density gradient ultracentrifugation work to separate DNA strands?

When a concentrated cesium chloride solution is subjected to hundreds of thousands of gravities in an ultracentrifuge, cesium ions migrate to the bottom, creating a continuous and stable physical density gradient along the tube. Suspended DNA macromolecules move until they are placed exactly in the band where their own buoyant density matches that of the saline solution, allowing distinguishing heavy and light DNA strands in molecular biology.

What did the serious Goiânia radiological accident caused by abandoned cesium-137 consist of?

In 1987, two scavengers looted an abandoned radiotherapy clinic in Goiânia (Brazil) and dismantled a teletherapy unit containing a capsule of cesium-137 chloride powder. Fascinated by the powder that glowed with a faint blue light in the darkness due to the Cherenkov effect, they showed it to family and neighbors. The dispersion of the radioactive powder contaminated hundreds of people, caused four immediate deaths and forced the demolition of homes and the burial of tons of nuclear debris.

How is cesium vapor used in the ion propulsion of space exploration probes?

Cesium was the pioneering propellant of space ion engines due to having the lowest ionization energy of stable elements (3.89 electronvolts) and a considerable atomic mass. By bringing cesium vapor into contact with a hot porous tungsten grid, cesium atoms spontaneously cede their electron to the metal and transform into positive ions. Electrostatic fields accelerate these ions to tremendous speeds toward outer space, generating a hyper-efficient continuous thrust.

Why does cesium melt with the heat of the hand?

Cesium has an exceptionally low melting point, only 28.5 °C. This means that on a hot summer day or holding a sealed glass ampoule in the palm of the hand, body heat melts the metal in a few minutes. In addition, it is one of the few metals with a beautiful pale golden luster, although it should never be touched directly due to its extreme reactivity.

Why are cesium formate brines so prized in offshore oil drilling?

Cesium formate is a monovalent organic salt with colossal water solubility, generating clear brines with densities of up to 2.3 grams per cubic centimeter without the need for suspended solid particles. In offshore oil and gas wells subjected to extreme pressures and temperatures (HPHT), this fluid lubricates the drill bit, balances the colossal reservoir pressure to prevent blowouts and does not damage the porous walls of the hydrocarbon-producing rock.

Why is cesium hydroxide cataloged as the most corrosive base that exists?

Cesium hydroxide (CsOH) combines the most voluminous and electropositive metallic cation of the periodic table with the hydroxide anion. The Cs-O bond is almost purely ionic, so in water it dissociates 100 % releasing hydroxide ions without any electrostatic restriction. This excessive basicity allows it to attack borosilicate glasses, corrode refractory ceramics and dissolve biological tissues with a thermal and chemical aggressiveness far superior to caustic soda or caustic potash.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.