Skip to main content
241.660
51.996 u+2, +3, +6
[Ar] 3d5 4s1CrChromium

Chromium

Chromium is a chemical element with symbol Cr and atomic number 24. It is the first element in Group 6. It is a steely-gray, lustrous, hard and brittle metal which takes a high polish, resists tarnishing, and has a high melting point.

Identity

Atomic mass
51.996 u
Category
Transition metals
Group
6
Period
4
Block
d
Oxidation States
+2, +3, +6
Phase (25 °C)
Solid
Appearance
silvery metallic

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s1 3d5
Short configuration
[Ar] 3d5 4s1
Electrons per shell
2, 8, 13, 1
Electronegativity (Pauling)
1.66
Electron affinity
65.2 kJ/mol
1st ionization energy
653 kJ/mol
Ionization energies
653 · 1591 · 2987 · 4743 · 6702… kJ/mol

Physical properties

Melting point
1906.8 °C (2180 K)
Boiling point
2670.8 °C (2944 K)
Density
7.19 g/cm³
Molar heat capacity
23.4 J/(mol·K)

Chemical behavior of chromium

Chromium is a transition metal of group 6 with symbol Cr and atomic number 24. It is a soft, silver-grey coloured, very hard, corrosion-resistant metal. It presents main oxidation states +2, +3 and +6, with +3 being the most stable and most common. It is an essential element for the stainless steel industry, pigments and electrodes.

Reactivity

  • 2 Cr + 3 Cl₂ → 2 CrCl₃

    Chromium reacts with chlorine to give chromium(III) chloride, a green solid that is the most stable chromium compound.

  • 2 Cr + 3 H₂SO₄ (hot) → Cr₂(SO₄)₃ + 3 H₂

    Chromium reacts with hot sulfuric acid, releasing hydrogen and forming chromium(III) sulfate.

Notable compounds

CompoundFormulaUse or importance
Chromium(III) chlorideCrCl₃Green solid; precursor of compounds and colouring agent
Chromium(III) oxideCr₂O₃Green solid; used as pigment, abrasive and in superhard films
Chromium(VI) trioxideCrO₃Red solid; strong oxidant, used in chemical reagents and lead dioxide

Electron shell distribution

Electron shell distribution diagram of Chromium.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.CrView in the atom builder

Isotopes

Natural chromium is composed of four stable isotopes: chromium-50 (⁵⁰Cr, 4.35%), chromium-52 (⁵²Cr, 83.79%), chromium-53 (⁵³Cr, 9.50%) and chromium-54 (⁵⁴Cr, 2.36%). Chromium-52 is the most abundant. In addition, radioactive isotopes are known, with chromium-51 being the most used in medical research.

Occurrence and production

Chromium is the 22nd most abundant element in the Earth's crust, with concentrations of 0.01% by mass. It appears in minerals such as Chromite (FeCr₂O₄) and spinel. The main reserves are in South Africa, Kazakhstan, Turkey, India and the Russian Federation. It is obtained mainly as a byproduct of nickel and iron production.

History and origin of the name

Chromium was discovered in 1797 by Louis Nicolas Vauquelin in France, who isolated it from a red-coloured rock together with calcite. The name derives from Greek 'chroma', meaning 'colour', in reference to the large number of colours of its compounds. It was the first element in group 6 of the periodic table.

Applications and relevance of chromium

Uses of the element

Chromium is used mainly in stainless steels, nitrogenised alloys, electrodes, decorative and industrial coatings, pigments, and in the manufacture of cutting tools. It is essential for modern metallurgy.

Uses of its compounds

Chromium is widely used in pigments (green, yellow, red) for paints, ceramics and plastics. As a catalyst in the manufacture of enoimo de acero. Meat and soil are natural sources of chromium in the environment.

Health, safety and environment

Biological role

Chromium is not essential for living things, although some species of bacteria can use chromium(VI) in certain respiration reactions. Most research indicates that chromium(III) is the most stable and predominant state in organisms, but its exact biological role is not completely clear. It can be necessary in small amounts in the body, although it is not completely confirmed that it is essential for humans.

Safety

Chromium metal is relatively stable and not very toxic. However, inorganic compounds of chromium(VI) are highly toxic and carcinogenic. Exposure to chromium dust can cause skin, eye and respiratory irritation. Chromium(VI) can damage kidneys, liver and nervous and reproductive systems.

Environment

Chromium does not degrade in the environment and can accumulate in soils and sediments. Chromium(VI) is highly toxic to aquatic life and can persist in water for long periods. Proper management of industrial waste is crucial to prevent environmental contamination.

Frequently asked questions about Chromium

Why does chromium make stainless steel resist corrosion?

Chromium is essential for the corrosion resistance of stainless steel because, when it comes into contact with oxygen, it contributes to forming a very thin and adherent surface layer rich in chromium. This layer makes it difficult for the metal to continue reacting with the environment and can regenerate if damaged, as long as conditions are appropriate. In general, stainless steels contain at least approximately 10.5% chromium by mass, although their specific resistance also depends on other elements and the media to which they are exposed.

Why are some chromium compounds used as pigments?

Certain chromium compounds present intense and relatively stable colours, so they have been used as pigments in paints, ceramics and other materials. Among the historical examples are yellow chromium lead chromate pigments and green chromium oxides. However, some traditional pigments contain hazardous substances and their use is restricted in many contexts. Chromium(III) oxide, in particular, stands out for its green colour and stability, which favours certain industrial and artistic applications.

Why is chromium oxide used in abrasives and polishes?

Chromium(III) oxide, formula Cr₂O₃, is a hard and chemically stable solid that can be used in certain polishing products. In the form of fine particles, it helps remove small surface imperfections and obtain smooth finishes on suitable materials, including certain metals. Its effectiveness depends on particle size, surface hardness and the procedure used. It is also used as a green pigment, so its presence in a product does not necessarily imply an abrasive function.

Why is chromium important in the manufacture of cutting tools?

Chromium is incorporated into numerous steels for tools because it contributes to improving temperability, wear resistance and, in certain compositions, corrosion resistance. These properties help manufacture blades, drills, dies and tools capable of maintaining performance during prolonged use. The result depends on the amount of chromium and its combination with elements such as carbon, molybdenum or vanadium, as well as heat treatment. Not all chromium steels offer the same performance, as they are designed for different tasks.

How is chromium used to coat metal surfaces?

Chroming consists of depositing a chromium layer on the surface of another material through a coating process, usually electrochemical. Depending on the type of treatment, it can provide a bright finish, improve wear resistance or reduce friction. Decorative chroming usually uses very thin layers, while hard chroming is used in industrial components subjected to friction. Surface preparation and process control are fundamental to obtaining a uniform layer with the desired properties.

What function does chromium have in heat-resistant alloys?

Chromium is part of many alloys designed to work at high temperatures because it helps improve oxidation resistance and resistance to certain corrosive environments. In superalloys used in turbines and industrial equipment, it contributes to protecting the surface against the formation of harmful oxides. Its effect depends on the complete composition of the alloy, as other elements provide mechanical resistance, microstructural stability or additional protection. That is why chromium content is adjusted according to temperature and service conditions.

How do chromium compounds participate in leather tanning processes?

Some chromium(III) salts are used in industrial leather tanning because they can interact with chemical groups of collagen, the structural protein of skin. These interactions help stabilise the material's structure and improve properties such as heat resistance and durability. The process requires controlling chemical conditions to obtain leather with the desired characteristics. It is important to distinguish chromium(III), used in tanning, from chromium(VI), which presents different toxicological risks and requires specific controls.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.