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62.550
[12.0096, 12.0116] u−4, +2, +4
[He] 2s2 2p2CCarbon

Carbon

Carbon (from Latin:carbo "coal") is a chemical element with symbol C and atomic number 6. On the periodic table, it is the first (row 2) of six elements in column (group) 14, which have in common the composition of their outer electron shell. It is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds.

Identity

Atomic mass
[12.0096, 12.0116] u
Category
Reactive non-metals
Group
14
Period
2
Block
p
Oxidation States
−4, +2, +4
Phase (25 °C)
Solid

Electronic Structure

Electron configuration
1s2 2s2 2p2
Short configuration
[He] 2s2 2p2
Electrons per shell
2, 4
Electronegativity (Pauling)
2.55
Electron affinity
122 kJ/mol
1st ionization energy
1.09e+3 kJ/mol
Ionization energies
1087 · 2353 · 4621 · 6223 · 37831… kJ/mol

Physical properties

Melting point
—
Boiling point
—
Density
1.821 g/cm³
Molar heat capacity
8.52 J/(mol·K)

Chemical behavior of carbon

Carbon has four valence electrons ([He] 2s² 2p²) and a medium electronegativity (2.55), so it can share, give up or capture electrons depending on its partner. Its singularity is concatenation: it forms chains and rings with itself through single, double and triple bonds, giving millions of compounds. It presents states −4, +2 and +4: +4 dominates with oxygen and halogens, −4 in carbides and methane, and +2 in carbon monoxide.

Reactivity

  • C + O₂ → CO₂

    In excess oxygen it burns completely giving carbon dioxide. It is the combustion that releases the energy of fossil fuels and biomass, the historical basis of human energy.

  • 2 C + O₂ → 2 CO

    With limited oxygen it forms carbon monoxide, a toxic gas and good reducing agent. In the blast furnace it reduces iron ore; in industry it feeds methanol synthesis and fuels.

  • C + 2 H₂ → CH₄

    With hydrogen, at high temperature and with catalyst, it forms methane. It is the reverse reaction of reforming: it illustrates the equilibrium between elemental carbon and hydrocarbons.

  • C + H₂O → CO + H₂

    Red-hot coal reacts with steam giving synthesis gas (CO + H₂), raw material for ammonia, methanol and synthetic fuels. It is the classic reaction of the gas generator.

Notable compounds

CompoundFormulaUse or importance
Carbon dioxideCO₂Photosynthesis and respiration; beverages, fire extinguishers and greenhouse effect
MethaneCH₄Natural gas; domestic fuel and chemical raw material
Calcium carbonateCaCO₃Limestone, marble; cement, glass and acidity correction
Carbon monoxideCOSiderurgical reducing agent; methanol and acetic acid synthesis
Silicon carbideSiCAbrasive and high-performance ceramics for electronics

Electron shell distribution

Electron shell distribution diagram of Carbon.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.CView in the atom builder

Isotopes

Natural carbon combines carbon-12 (¹²C), with six neutrons and 98.9%, and carbon-13 (¹³C), with seven neutrons and 1.1%. ¹²C defines the atomic mass unit. Carbon-14 (¹⁴C), with eight neutrons, is radioactive (5,730-year half-life), forms in the atmosphere and dates organic remains up to 50,000 years.

Occurrence and production

It is the fourth element in the universe but scarce in the crust (about 200 ppm), concentrated in carbonates, fossil fuels, atmospheric CO₂ and biomass. Its native forms are graphite and diamond. It is obtained by mining (coal, graphite, diamond) and from the atmosphere and biomass for organic chemistry; synthetic graphite and nanotubes are made at high temperature.

History and origin of the name

Known since prehistory as coal, soot and diamond, Lavoisier proved in 1789 that diamond is pure carbon by burning it and obtaining CO₂. Jöns Jacob Berzelius fixed its symbol C and Davy confirmed its elemental nature. In 1860 August Kekulé and Couper founded organic chemistry on its four bonds, and in 1985 fullerenes were discovered.

Applications and relevance of carbon

Uses of the element

As graphite it forms electrodes, lubricants, nuclear moderators and batteries; as diamond, abrasives, drills and jewellery; and in carbon fibres, ultralight materials for aviation and sport. Soot reinforces tyres and inks.

Uses of its compounds

Hydrocarbons are fuels and raw material for plastics, drugs and fertilisers; CO₂ feeds greenhouses and extinguishers; carbonates give cement, glass and paper; silicon carbide is used in power electronics.

Health, safety and environment

Biological role

It is the skeleton of life: all biomolecules (proteins, DNA, sugars, lipids) are carbon chains. CO₂ regulates respiration and blood pH through bicarbonate.

Safety

CO is lethal because it blocks haemoglobin with 200 times more affinity than oxygen; CO₂ asphyxiates in enclosed spaces; coal dust causes pneumoconiosis. Diamond and graphite are harmless.

Environment

The carbon cycle sustains the climate: burning fossil fuels raises atmospheric CO₂ (from 280 to 420 ppm since 1750) and acidifies oceans. Deforestation and livestock methane worsen warming; capturing CO₂ and decarbonising are the central challenges.

Frequently asked questions about Carbon

Why are diamond and graphite so different if both are carbon?

Diamond and graphite are carbon allotropes: they are made of the same element, but their atoms are arranged differently. In diamond, each atom is joined to four neighbours in a very rigid three-dimensional network, giving extreme hardness and electrical insulation. In graphite, atoms form layers that can slide, so it is soft, lubricating and conductive. Structure, not just composition, determines their properties.

Is carbon good or bad for the environment?

Carbon is neither good nor bad by itself: it is the basis of life and forms part of CO₂, fossil fuels and all living organisms. The environmental problem arises when large amounts of carbon stored for millions of years are released through oil, coal or natural gas, increasing greenhouse gases. The natural carbon cycle includes photosynthesis, respiration and decomposition; human activity has altered its balance.

Does graphite conduct electricity?

Yes. Graphite conducts electricity because its electrons can move relatively easily within its layers of carbon atoms. This property, together with its thermal stability, makes it useful in electrodes, batteries, motor brushes and electrical components. Diamond, on the other hand, is an electrical insulator under normal conditions because its electrons are strongly bonded in a three-dimensional network. Both are pure carbon, but their atomic arrangement produces opposite electrical behaviours.

Can graphite be converted into diamond?

In theory, graphite can be transformed into diamond, but it requires very high pressure and temperature conditions, similar to those of the Earth's interior, or controlled industrial processes. It does not occur spontaneously at room temperature because the transformation needs to overcome a significant energy barrier. There are synthesis methods of diamond, such as high pressure and high temperature or chemical vapour deposition, that produce diamonds for industrial tools, optics and, in some cases, jewellery.

What is the carbon footprint?

The carbon footprint is the total amount of greenhouse gases emitted directly or indirectly by a person, company, product or activity, usually expressed in tonnes of carbon dioxide equivalent. It includes, for example, energy consumption, transport, manufacturing of goods and waste management. Reducing it implies improving energy efficiency, using cleaner transport, consuming more responsibly and resorting to renewable energies. It should not be confused with the element carbon itself.

What is activated charcoal used for?

Activated charcoal is a form of carbon with an extremely porous internal surface, capable of adsorbing molecules. It is used in water and air filters, masks, purification systems, effluent treatment and some pharmaceuticals. Its effectiveness depends on the type of contaminant, contact time and filter design. It does not remove all contaminants equally and must be replaced periodically, as once saturated it loses its retention capacity.

What is graphene and how does it differ from graphite?

Graphene is a single layer of carbon atoms arranged in a two-dimensional hexagonal network; graphite is formed by many of these layers stacked. That is why graphene is extremely thin, light, flexible and an excellent electrical and thermal conductor. It is investigated for screens, batteries, sensors, composite materials and advanced electronics. Although it comes from graphite—actually, it can be obtained by separating its layers—its properties and potential applications are very different.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.