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832.020
208.98 u+3, +5
[Xe] 4f14 5d10 6s2 6p3BiBismuth

Bismuth

Bismuth is a chemical element with symbol Bi and atomic number 83. Bismuth, a pentavalent post-transition metal, chemically resembles arsenic and antimony. Elemental bismuth may occur naturally, although its sulfide and oxide form important commercial ores.

Identity

Atomic mass
208.98 u
Category
Post-transition metals
Group
15
Period
6
Block
p
Oxidation States
+3, +5
Phase (25 °C)
Solid
Appearance
lustrous silver

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p3
Short configuration
[Xe] 4f14 5d10 6s2 6p3
Electrons per shell
2, 8, 18, 32, 18, 5
Electronegativity (Pauling)
2.02
Electron affinity
90.9 kJ/mol
1st ionization energy
703 kJ/mol
Ionization energies
703 · 1610 · 2466 · 4370 · 5400… kJ/mol

Physical properties

Melting point
271.6 °C (545 K)
Boiling point
1563.8 °C (1837 K)
Density
9.78 g/cm³
Molar heat capacity
25.5 J/(mol·K)

Chemical behavior of bismuth

Bismuth has an electronic configuration [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p³. Its oxidation states are +3 (the most stable and common) and +5 (strongly oxidising). It belongs to group 15 (pnictogens) and is the most singular heavy metal in the periodic table: a brittle silver-white metal with a subtle iridescent pink tint. It is the most diamagnetic of all known metals and boasts the lowest thermal conductivity of all metals except mercury. Unlike its toxic neighbours of period 6 (lead, thallium, mercury and polonium), bismuth is notably non-toxic and biocompatible.

Reactivity

  • 4 Bi + 3 O₂ → 2 Bi₂O₃

    When heated to redness in air it burns with a brilliant blue flame forming yellow trioxide of bismuth; as it slowly cools on the surface it forms nanometric oxide layers with iridescent colours of the rainbow due to optical interference.

  • Bi³⁺ + Cl⁻ + H₂O ⇌ BiOCl + 2 H⁺

    Its aqueous salt solutions easily hydrolyse precipitating white insoluble and brilliant bismuth oxychloride.

  • Bi + 4 HNO₃ → Bi(NO₃)₃ + NO + 2 H₂O

    It dissolves easily in dilute nitric acid, releasing nitrogen monoxide and generating bismuth(III) nitrate.

  • Bi (líquido) → Bi (sólido) [expansión volumétrica 3,3 %]

    When passing from liquid to solid it experiences an anomalous volume expansion of 3.3% (similar to water), filling intricate moulds.

Notable compounds

CompoundFormulaUse or importance
Subsalicylate of bismuthC₇H₅BiO₄Gastrointestinal drug antacid and antidiarrhoeal over-the-counter (Pepto-Bismol) that fights Helicobacter pylori infections
Bismuth oxychlorideBiOClPearl white; synthetic cosmetic pigment with nacreous shine used in eyeshadows, lipsticks and nail polishes
Bismuth tellurideBi₂Te₃High performance thermoelectric material used in Peltier effect cells for electronics cooling without compressor
Bismuth trioxideBi₂O₃Dense ceramic material used in lead-free vitreous enamels and root canal dental filling cements (MTA)

Electron shell distribution

Electron shell distribution diagram of Bismuth.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.BiView in the atom builder

Isotopes

Traditionally considered the stable last element of the periodic table, in 2003 scientists from the French Institute of Space Astrophysics (France) discovered that its only primordial isotope, bismuth-209 (²⁰⁹Bi, with 126 magic neutrons), is actually an alpha-emitting radioisotope with a colossal half-life of 1.9 × 10¹⁹ years (about 19 trillion years, more than a billion times the age of the universe). Synthetic radioisotopes are known; bismuth-213 (²¹³Bi, half-life of 45.6 minutes) is used in nuclear medicine for alpha therapy against leukaemias.

Occurrence and production

It is a scarce element in the Earth's crust (about 0.02-0.08 ppm), twice as abundant as gold. It occasionally appears as free native metal in hydrothermal veins with silver and cobalt minerals, but its main commercial ores are bismuthinite (bismuth sulphide, Bi₂S₃) and bismite (bismuth trioxide). The huge majority of world bismuth is recovered as a byproduct of lead, copper, tin and tungsten metallurgical refining, mainly in China, Vietnam and Mexico.

History and origin of the name

Although in the Middle Ages and Renaissance it was often confused with lead, tin and antimony, German miners in Saxony knew it as 'Wismut' (white meadow or white mass) in the 15th century. In 1527 Paracelsus described it as a singular metal and in 1753 the French chemist Claude François Geoffroy demonstrated definitively that it was an independent chemical element with its own properties distinct from lead and tin.

Applications and relevance of bismuth

Uses of the element

Due to its anomalous volume expansion on solidification and its low melting point (271.4 °C), bismuth forms fusible eutectic alloys (such as Wood's alloy, Rose's alloy and Field's alloy) used in automatic fire sprinkler systems, safety fuses and boiler plugs. It substitutes lead in ecological fishing leads, non-toxic hunting shot and lead-free plumbing fittings.

Uses of its compounds

Subsalicylate of bismuth is the most consumed gastrointestinal remedy against acidity and traveller's diarrhoea; bismuth oxychloride adds pearlescent shine to cosmetics; and bismuth telluride powers solid-state thermoelectric coolers.

Health, safety and environment

Biological role

It is not essential for any living being. It is extraordinarily harmless compared to other heavy metals of its period: bismuth ion does not accumulate in the body and is easily excreted by renal and faecal route without causing systemic organ damage at usual therapeutic doses.

Safety

It is a safe metal to handle. In pharmacology, ingestion of subsalicylate of bismuth causes a striking but harmless temporary black colouration of faeces and tongue due to formation of traces of bismuth sulfide with digestive sulfur.

Environment

It is the ideal ecological substitute ('green metal') to eliminate lead in fishing weights, wheel counterweights and electronic soldering, avoiding saturnism and pollution of birds and river courses.

Frequently asked questions about Bismuth

Why do bismuth crystals have rainbow colours and stepped shapes?

When bismuth liquid cools slowly, the edges of the crystal grow faster than the central faces, forming striking stepped pyramid-shaped bulges. When it is taken out into the hot air, the metal immediately oxidises creating a thin transparent film. Light reflects between the oxide surface and the metal, producing optical interferences with vivid yellow, purple and blue reflections.

How does subsalicylate of bismuth fight the stomach bacterium Helicobacter pylori?

In the treatment of peptic ulcer and gastritis, subsalicylate of bismuth acts by a triple mechanism: it covers the eroded gastric mucosa with a protective film against digestive acids, stimulates the secretion of endogenous prostaglandins and exerts a direct bactericidal action. Bismuth ions penetrate the Helicobacter pylori bacterium and inhibit key respiratory enzymes and adhesions, destroying the bacterial cell wall and eradicating the infection in combined therapies.

How do bismuth telluride devices refrigerate microchips?

Peltier cooling cells use bismuth telluride semiconductors (Bi₂Te₃) doped p and n type joined in series electrically. When a direct current crosses the semiconductor junctions, electrons absorb thermal energy on one side and transfer it to the opposite side by Peltier effect. This allows computer processors, astronomical cameras and portable fridges to be cooled silently without mechanical motors, refrigerant liquids or greenhouse gases.

How does the radioisotope bismuth-213 act in alpha therapy against tumour cells?

Bismuth-213 is an alpha radionuclide with short half-life (46 minutes) produced in actinium-225 generators. In nuclear medicine it is chemically bound to monoclonal antibodies designed to anchor exclusively on the surface of leukaemic cells or micrometastases. Upon decay, it emits a high-energy alpha particle that destroys the DNA of the cancer cell in a microscopic path of a few healthy cells' distance, minimising damage to neighbouring tissues.

How was it proven in 2003 that bismuth-209 is slightly radioactive after being considered stable?

For more than a century it was believed that bismuth-209 was the heaviest stable element in nature. In 2003, French scientists enclosed pure bismuth germanate crystals in cryogenic thermal detectors at just twenty-thousandths of a degree above absolute zero in a underground laboratory. After weeks of environmental silence, they detected the minuscule alpha decay signal with a half-life of nineteen trillion years, confirming that technically all bismuth is radioactive.

Why does bismuth increase in size when it solidifies?

Almost all metals contract and occupy less space when they cool and pass from liquid to solid. Bismuth is one of the few exceptions of nature, behaving like water when it freezes: when solidifying, its atoms reorganise into a more open and spacious crystal lattice, increasing its volume by more than three percent. This property is ideal for melting intricate pieces and printing types.

Why does bismuth levitate over strong magnets due to its enormous diamagnetism?

Diamagnetism is the property by which a material induces an opposite magnetic field inside it to the applied external field, experiencing a repulsive force. Bismuth has delocalised electrons with a very small effective mass that circulate with great freedom, giving it the greatest diamagnetic susceptibility of all metals. If a bismuth sheet is placed between strong neodymium magnets, the repulsive force overcomes gravity, making it levitate in the air.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.