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18—
[39.792, 39.963] u0
[Ne] 3s2 3p6ArArgon

Argon

Argon is a chemical element with symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most common gas in the Earth's atmosphere, at 0.934% (9,340 ppmv), making it over twice as abundant as the next most common atmospheric gas, water vapor (which averages about 4000 ppmv, but varies greatly), and 23 times as abundant as the next most common non-condensing atmospheric gas, carbon dioxide (400 ppmv), and more than 500 times as abundant as the next most common noble gas, neon (18 ppmv).

Identity

Atomic mass
[39.792, 39.963] u
Category
Noble gases
Group
18
Period
3
Block
p
Oxidation States
0
Phase (25 °C)
Gas
Appearance
colorless gas exhibiting a lilac/violet glow when placed in a high voltage electric field

Electronic Structure

Electron configuration
1s2 2s2 2p6 3s2 3p6
Short configuration
[Ne] 3s2 3p6
Electrons per shell
2, 8, 8
Electronegativity (Pauling)
—
Electron affinity
-96 kJ/mol
1st ionization energy
1.52e+3 kJ/mol
Ionization energies
1521 · 2666 · 3931 · 5771 · 7238… kJ/mol

Physical properties

Melting point
-189.3 °C (84 K)
Boiling point
-185.8 °C (87 K)
Density
0.001784 g/cm³
Molar heat capacity
—

Chemical behavior of argon

Argon is a noble gas of group 18 with symbol Ar and atomic number 18. It is the third most abundant gas in Earth's atmosphere (about 0.93%). It is harmless, colorless, odorless and extremely unreactive. It has an oxidation state of 0 and does not form stable compounds with other elements.

Reactivity

  • Ar -> no reaction

    Argon is an inert noble gas: it does not react with other elements or compounds under normal conditions.

  • Ar does not chemically decompose

    Its valence shell is complete (2s² 2p⁶), which gives it maximum stability and very little tendency to gain or lose electrons.

Notable compounds

CompoundFormulaUse or importance
Argon difluorideArF₂Excited-state compound used in discharge lasers; not a stable compound under normal conditions
Argon ion (ArF⁺)ArF⁺Ionic radical intermediate in plasma and laser processes

Electron shell distribution

Electron shell distribution diagram of Argon.Bohr-style diagram: the nucleus sits at the center and the electrons are arranged on concentric circular orbits, one per energy level.ArView in the atom builder

Isotopes

Natural argon consists of three stable isotopes: argon-40 (⁴⁰Ar, about 99.6%), argon-38 (³⁸Ar, 0.06%) and argon-36 (³⁶Ar, 0.34%). Argon-40 is formed by the decay of potassium-40 (⁴⁰K) and is the basis of the potassium-argon dating method in geology.

Occurrence and production

Argon makes up about 0.93% of Earth's atmosphere by volume, making it the third most abundant gas. It appears mainly as a byproduct of crude-oil refining through fractional distillation. It also occurs in natural-gas fields in small amounts.

History and origin of the name

Argon was discovered in 1894 by Lord Rayleigh and Sir William Ramsay in the United Kingdom. They identified it by analyzing the difference between the density of nitrogen obtained from liquid air and atmospheric nitrogen. They isolated it by removing oxygen and carbon dioxide from the air and absorbing nitrogen oxides. It was the first noble gas discovered and was named after the Greek root „argos“, meaning „inactive“ or „sleeping“.

Applications and relevance of argon

Uses of the element

Argon is mainly used in industrial and scientific applications: as a protective atmosphere in welding (TIG, MIG), in gas lasers, in the conservation of historical documents, as a filling in double-glazed windows, and in particle detectors in nuclear physics.

Uses of its compounds

Argon compounds are scarce and only form under specialized conditions. Argon difluoride (ArF₂) is used in ultraviolet lasers and as an intermediate in some industrial plasma and laser processes.

Health, safety and environment

Biological role

Argon is not essential for living beings and has no known toxicity. At high concentrations, it can act as asphyxiant by displacing oxygen from the air, causing respiratory difficulty, loss of consciousness, or even death in closed environments without adequate ventilation.

Safety

Argon is a colorless, odorless gas that can displace oxygen in enclosed spaces. Adequate ventilation and oxygen monitoring are required in areas where liquid argon or pressurized argon is handled. Contact with liquid argon can cause cold burns (cryogenic burns). Industrial argon waste should be handled according to safety standards.

Environment

Argon is harmless to the environment in its natural forms. Its industrial emissions do not cause chemical pollution, but argon production by air distillation uses energy, so its carbon footprint depends on the energy source. As a noble gas, it does not degrade or accumulate in the ecosystem.

Frequently asked questions about Argon

Why is argon used to weld metals?

Argon creates a protective atmosphere around the metal during certain welding processes. By displacing the air from the work area, it reduces the contact of hot metal with oxygen and other components that could cause oxidation or alter the quality of the joint. That is why it is used especially in techniques such as TIG and MIG, although the appropriate gas mixture depends on the metal and the process used. Its chemical stability allows work with materials sensitive to contamination.

How does argon help to preserve documents and old objects?

Argon can be used to create protective atmospheres around materials sensitive to certain chemical reactions. By reducing the presence of oxygen, it helps limit some oxidation processes that can degrade metals, historical components or especially delicate objects. Its usefulness depends on the characteristics of the material and the conservation conditions, as it does not prevent all degradation mechanisms. In specialized applications, a controlled atmosphere allows pieces to be kept in more stable conditions during storage or treatment.

How does argon help to determine the age of some rocks?

In geochronology, the potassium-argon system takes advantage of the fact that the radioactive isotope potassium-40 transforms, through different decay pathways, into other nuclei including argon-40. When a rock cools and begins to retain argon, the accumulated amount can provide information about the time elapsed since that isotopic closure. Measurements must take into account possible subsequent losses or incorporations of argon. This technique, along with variants such as argon-argon dating, allows investigation of geological processes and the chronology of volcanic materials.

Why is argon useful in physics experiments?

Argon is used in particle detectors and nuclear physics experiments because it can record the passage of ionizing radiation. In liquid argon detectors, particles that pass through the material produce ionization and, under certain conditions, light flashes that can be measured. These signals help to reconstruct the energy and trajectory of the incident particles. Its use requires specialized systems to keep argon in liquid state and collect very weak signals, allowing the study of physical phenomena difficult to observe directly.

What is argon plasma and how is it generated?

Argon plasma is a gas energized in which a part of the atoms is ionized, producing free electrons and ions. It can be generated by applying sufficient energy through an electric discharge or electromagnetic field. In this state, argon can conduct electricity and reach high temperatures, making it useful in industrial and experimental processes. Its properties depend on pressure, applied power and degree of ionization, allowing the plasma to be adapted to different applications.

Why is argon used in some lasers?

Argon can be part of gas lasers in which an electric discharge excites its atoms or ions. In the well-known argon ion lasers, certain electronic transitions produce visible radiation, especially in blue and green regions of the spectrum. These devices have been used in research, spectroscopy and specialized medical applications. Their operation requires adequate power and cooling systems, so in many applications they have been replaced by more compact and efficient laser technologies.

Why is argon used in double-glazing?

In some double or triple glazing, the space between the panels is filled with argon to reduce heat transfer. Its thermal conductivity is lower than that of air under comparable conditions, which can improve window insulation. The result also depends on the width of the chamber, the glass coatings and the quality of the seal. Argon therefore contributes to energy efficiency, but does not by itself determine the thermal performance of the entire window.

Main sources consulted: PubChem, Royal Society of Chemistry, NIST, IUPAC. Last revision: November 2026.